Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and PowerLeeds, F. H. (Frank Henley)
Science
Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and Power
Leeds, F. H. (Frank Henley)
Acetylene
According to Lewes, the maximum amount of ammonia found in the acetylene
coming from a dripping generator is 0.95 gramme per litre, while in
carbide-to-water gas it is 0.16 gramme: 417 and 70.2 grains per cubic
foot respectively. Rossel and Landriset have found 4 milligrammes (1.756
grains [Footnote: Milligrammes per litre; grains per cubic foot. It is
convenient to remember that since 1 cubic foot of water weighs 62.321 x
16 - 997.14 avoirdupois ounces, grammes per litre are approximately equal
to oz. per cubic foot; and grammes per cubic metre to oz. per 1000 cubic
feet.]) to be the maximum in water-to-carbide gas, and none to occur in
carbide-to-water acetylene. Rossel and Landriset return the minimum
proportion of sulphur, calculated as H_2S, found in the gaseous state in
acetylene when the carbide has not been completely flooded with water at
1.18 milligrammes per litre, or 0.52 grain per cubic foot; and the
corresponding maxima at 1.9 milligrammes, or 0.84 grain. In carbide-to-
water gas, the similar maxima are 0.23 milligramme or 0.1 grain. As
already stated, the highest proportion of phosphine yet found in
acetylene is 2.3 per cent. (Lewes), which is equal to 32.2 milligrammes
of PH_3 per litre or 14.13 grains per cubic foot (Polis); but this sample
dated from 1897. Eitner and Keppeler record the minimum proportion of
phosphorus, calculated as PH_3, found in crude acetylene, as 0.45
milligramme per litre, and the maximum as 0.89 milligramme per litre; in
English terms these figures are 0.2 and 0.4 grain per cubic foot. On an
average, however, British and Continental carbide of the present day may
be said to give a gas containing 0.61 milligramme of phosphorus
calculated as PH_3 per litre and 0.75 milligramme of sulphur calculated
as H_2S. In other units these figures are equal to 0.27 grain of PH_3 and
0.33 grain of H_2S per 1 cubic foot, or to 0.041 per cent. by volume of
PH_3 and 0.052 per cent. of H_2S. Yields of phosphorus and sulphur much
higher than these will be found in the journals and books, but such
analytical data were usually obtained in the years 1896-99, before the
manufacture of calcium carbide had reached its present degree of
systematic control. A commercial specimen of carbide was seen by one of
the authors as late as 1900 which gave an acetylene containing 1.12
milligramme of elementary sulphur per litre, i.e., 0.096 per cent, by
volume, or 0.102 per cent, by volume of H_2S; but the phosphorus showed
the low figure of 0.36 milligramme per litre (0.031 per cent, of P or
0.034 per cent, of PH_3 by volume).
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