Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and PowerLeeds, F. H. (Frank Henley)
Science
Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and Power
Leeds, F. H. (Frank Henley)
Acetylene
The ITALIAN GOVERNMENT rules relating to the storage and transport of
carbide follow in the main those of the Austrian Government, but for
quantities between 300 and 2000 kilos sanction is required from the local
authorities, and for larger quantities from superior authorities. The
storage of quantities ranging from 300 to 2000 kilos is forbidden in
dwelling-houses and above the latter quantity the storage-place must be
isolated and specially selected. No special permit is required for the
storage of quantities not exceeding 300 kilos. Workmen exposed to carbide
dust arising from the breaking of carbide or otherwise must have their
eyes and respiratory organs suitably protected.
THE PURCHASE OF CARBIDE.--Since calcium carbide is only useful as a means
of preparing acetylene, it should be bought under a guarantee (1) that it
contains less impurities than suffice to render the crude gas dangerous
in respect of spontaneous inflammability, or objectionable in a manner to
be explained later on, when consumed; and (2) that it is capable of
evolving a fixed minimum quantity of acetylene when decomposed by water.
Such determination, however, cannot be carried out by the ordinary
consumer for himself. A generator which is perfectly satisfactory in
general behaviour, and which evolves a sufficient proportion of the
possible total make of gas to be economical, does not of necessity
decompose the carbide quantitatively; nor is it constructed in a fashion
to render an exact measurement of the gas liberated at standard
temperature and pressure easy to obtain. For obvious reasons the careful
consumer of acetylene will keep a record of the carbide decomposed and of
the acetylene generated--the latter perhaps only in terms of burner-
hours, or the like; but in the event of serious dispute as to the gas-
making capacity of his raw material, he must have a proper analysis made
by a qualified chemist.
Calcium carbide is crushed by the makers into several different sizes, in
each of which all the lumps exceed a certain size and are smaller than
another size. It is necessary to find out by experiment, or from the
maker, what particular size suits the generator best, for different types
of apparatus require different sizes of carbide. Carbide cannot well be
crushed by the consumer of acetylene. It is a difficult operation, and
fraught with the production of dust which is harmful to the eyes and
throat, and if done in open vessels the carbide deteriorates in gas-
making power by its exposure to the moisture of the atmosphere. True dust
in carbide is objectionable, and practically useless for the generation
of acetylene in any form of apparatus, but carbide exceeding 1 inch in
mesh is usually sold to satisfy the suggestions of the British Acetylene
Association, which prescribes 5 per cent, of dust as the maximum. Some
grades of carbide are softer than others, and therefore tend to yield
more dust if exposed to a long journey with frequent unloadings.
Public-domain text, read in full here on John Shaqi.
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