Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and PowerLeeds, F. H. (Frank Henley)
Science
Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and Power
Leeds, F. H. (Frank Henley)
Acetylene
Hitherto, for the sake of simplicity, the by-product in the preparation
of acetylene has been described as calcium oxide or quicklime. It is,
however, one of the leading characteristics of this body to be
hygroscopic, or greedy of moisture; so that if it is brought into the
presence of water, either in the form of liquid or as vapour, it
immediately combines therewith to yield calcium hydroxide, or slaked
lime, whose chemical formula is Ca(OH)_2. Accordingly, in actual
practice, when calcium carbide is mixed with an excess of water, a
secondary reaction takes place over and above that indicated by equation
(1), the quicklime produced combining with one chemical part or molecule
of water, thus--
CaO + H_2O = Ca(OH)_2.
As these two actions occur simultaneously, it is more usual, and more in
agreement with the phenomena of an acetylene generator, to represent the
decomposition of calcium carbide by the combined equation--
(2) CaC_2 + 2H_2O = C_2H_2 + Ca(OH)_2.
By the aid of calculations analogous to those employed in the preceding
paragraph, it will be noticed that equation (2) states that 1 molecule of
calcium carbide, or 64 parts by weight, combines with 2 molecules of
water, or 36 parts by weight, to yield 1 molecule, or 26 parts by weight
of acetylene, and 1 molecule, or 74 parts by weight of calcium hydroxide
(slaked lime). Here again, if more than 36 parts of water are taken for
every 64 parts of calcium carbide, the excess of water over those 36
parts is left undecomposed; and in the same fashion, if less than 36
parts of water are taken for every 64 parts of calcium carbide, some of
the latter must remain unattacked, whilst, obviously, the amount of
acetylene liberated cannot exceed that which corresponds with the
quantity of substance suffering complete decomposition. If, for example,
the quantity of water present in a generator is more than chemically
sufficient to attack all the carbide added, however largo or small that
excess may be, no more, and, theoretically speaking, no less, acetylene
can ever be evolved than 26 parts by weight of gas for every 64 parts by
weight of calcium carbide consumed. It is, however, not correct to invert
the proposition, and to say that if the carbide is in excess of the water
added, no more, and, theoretically speaking, no less, acetylene can ever
be evolved than 26 parts by weight of gas for every 36 parts of water
consumed, as might be gathered from equation (2); because equation (1)
shows that 26 parts of acetylene may, on occasion, be produced by the
decomposition of 18 parts by weight of water. From the purely chemical
point of view this apparent anomaly is explained by the circumstance that
of the 36 parts of water present on the left-hand aide of equation (2),
only one-half, _i.e._, 18 parts by weight, are actually decomposed
into hydrogen and oxygen, the other 18 parts remaining unattacked, and
merely attaching themselves as "water of hydration" to the 56 parts of
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