Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and PowerLeeds, F. H. (Frank Henley)
Science
Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and Power
Leeds, F. H. (Frank Henley)
Acetylene
calcium oxide in equation (1) so as to produce the 74 parts of calcium
hydroxide appearing on the right-hand side of equation (2). The matter is
perhaps rendered more intelligible by employing the old name for calcium
hydroxide or slaked lime, viz., hydrated oxide of calcium, and by writing
its formula in the corresponding form, when equation (2) becomes
CaC_2 + 2H_2O = C_2H_2 + CaO.H_2O.
It is, therefore, absolutely correct to state that if the amount of
calcium carbide present in an acetylene generator is more than chemically
sufficient to decompose all the water introduced, no more, and
theoretically speaking no less, acetylene can ever be liberated than 26
parts by weight of gas for every 18 parts by weight of water attacked.
This, it must be distinctly understood, is the condition of affairs
obtaining in the ideal acetylene generator only; since, for reasons which
will be immediately explained, when the output of gas is measured in
terms of the water decomposed, in no commercial apparatus, and indeed in
no generator which can be imagined fit for actual employment, does that
output of gas ever approach the quantitative amount; but the volume of
water used, if not actually disappearing, is always vastly in excess of
the requirements of equation (2). On the contrary, when the make of gas
is measured in terms of the calcium carbide consumed, the said make may,
and frequently does, reach 80, 90, or even 99 per cent. of what is
theoretically possible. Inasmuch as calcium carbide is the one costly
ingredient in the manufacture of acetylene, so long as it is not wasted--
so long, that is to say, as nearly the theoretical yield of gas is
obtained from it--an acetylene generator is satisfactory or efficient in
this particular; and except for the matter of solubility discussed in the
following chapter, the quantity of water consumed is of no importance
whatever.
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