Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and PowerLeeds, F. H. (Frank Henley)
Science
Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and Power
Leeds, F. H. (Frank Henley)
Acetylene
HEAT EVOLVED IN THE REACTION.--The chemical reaction between calcium
carbide and water is accompanied by a large evolution of heat, which,
unless due precautions are taken to prevent it, raises the temperature of
the substances employed, and of the apparatus containing them, to a
serious and often inconvenient extent. This phenomenon is the most
important of all in connexion with acetylene manufacture; for upon a
proper recognition of it, and upon the character of the precautions taken
to avoid its numerous evil effects, depend the actual value and capacity
for smooth working of any acetylene generator. Just as, by an immutable
law of chemistry, a given weight of calcium carbide yields a given weight
of acetylene, and by no amount of ingenuity can be made to produce either
more or less; so, by an equally immutable law of physics, the
decomposition of a given weight of calcium carbide by water, or the
decomposition of a given weight of water by calcium carbide, yields a
perfectly definite quantity of heat--a quantity of heat which cannot be
reduced or increased by any artifice whatever. The result of a production
of heat is usually to raise the temperature of the material in which it
is produced; but this is not always the case, and indeed there is no
necessary connexion or ratio between the quantity of heat liberated in
any form of chemical reaction--of which ordinary combustion is the
commonest type--and the temperature attained by the substances concerned.
This matter has so weighty a bearing upon acetylene generation, and
appears to be so frequently misunderstood, that a couple of illustrations
may with advantage be studied. If a vessel full of cold water, and
containing also a thermometer, is placed over a lighted gas-burner, at
first the temperature of the liquid rises steadily, and there is clearly
a ratio between the size of the flame and the speed at which the mercury
mounts up the scale. Finally, however, the thermometer indicates a
certain point, viz., 100° C, and the water begins to boil; yet although
the burner is untouched, and consequently, although heat must be passing
into the vessel at the same rate as before, the mercury refuses to move
as long as any liquid water is left. By the use of a gas meter it might
be shown that the same volume of gas is always consumed (_a_) in
raising the temperature of a given quantity of cold water to the boiling-
point, and another equally constant volume of gas is always consumed
(_b_) in causing the boiling water to disappear as steam. Hence, as
coal-gas is assumed for the present purpose to possess invariably the
same heating power, it appears that the same quantity of heat is always
needed to convert a given amount of cold water at a certain temperature
into steam; but inasmuch as reference to the meter would show that about
5 times the volume of gas is consumed in changing the boiling water into
steam as is used in heating the cold water to the boiling-point, it will
Public-domain text, read in full here on John Shaqi.
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