Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and PowerLeeds, F. H. (Frank Henley)
Science
Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and Power
Leeds, F. H. (Frank Henley)
Acetylene
description; or it may be allowed to run down a depending pipe in
obedience to the law of gravitation, and stopped from running down such a
pipe by opposing to its passage a gas pressure superior to that
gravitational force. In any one of several obvious ways the supply of
water to a mass of carbide may be controlled with absolute certainty, and
therefore it should apparently follow that the make of acetylene should
be under perfect control by controlling the water current. On the other
hand, unless made up into balls or cartridges of some symmetrical form,
calcium carbide exists in angular masses of highly irregular shape and
size. Its lumps alter in shape and size directly liquid water or moisture
reaches them; a loose more or loss gritty powder, or a damp cohesive mud,
being produced which is well calculated to choke any narrow aperture or
to jam any moving valve. It is more difficult, therefore, by mechanical
agency to add a supply of carbide to a mass of water than to introduce a
supply of water to a stationary mass of carbide; and far more difficult
still to bring the supply of carbide under perfect control with the
certainty that the movement shall begin and stop immediately the proper
time arrives.
But assuming the mechanical difficulties to be satisfactorily overcome,
the plan of adding carbide to a stationary mass of water has several
chemical advantages, first, because, however the generator be
constructed, water will be in excess throughout the whole time of gas
production; and secondly, because the evolution of acetylene will
actually cease completely at the moment when the supply of carbide is
interrupted. There is, however, one particular type of generator in which
as a matter of fact the carbide is the moving constituent, viz., the
"dipping" apparatus (cf. _infra_), to which these remarks do not
apply; but this machine, as will be seen directly, is, illogically
perhaps, but for certain good reasons, classed among the water-to-carbide
apparatus. All the mechanical advantages are in favour, as just
indicated, of making water the moving substance; and accordingly, when
classified in the present manner, a great majority of the generators now
on the markets are termed water-to-carbide apparatus. Their disadvantages
are twofold, though these may be avoided or circumvented: in all types
save one the carbide is in excess at the immediate place and time of
decomposition; and in all types without exception the carbide in the
whole of the generator is in excess, so that the phenomenon of "after-
generation" occurs with more or less severity. As explained in the last
chapter, after-generation is the secondary production of acetylene which
takes place more or less slowly after the primary reaction is finished,
proceeding either between calcium hydroxide, merely damp lime, or damp
gas and calcium carbide, with an evolution of more acetylene. As it is
possible, and indeed usual, to fit a holder of some capacity even to an
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