Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and PowerLeeds, F. H. (Frank Henley)
Science
Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and Power
Leeds, F. H. (Frank Henley)
Acetylene
automatic generator, the simple fact that more acetylene is liberated
after the main reaction is over does not matter, for the gas can be
safely stored without waste and entirely without trouble or danger. The
real objection to after-generation is the difficulty of controlling the
temperature and of dissipating the heat with which the reaction is
accompanied. It will be evident that the balance of advantage, weighing
mechanical simplicity against chemical superiority, is somewhat even
between carbide-to-water and water-to-carbide generators of the proper
type; but the balance inclines towards the former distinctly in the ease
of non-automatic apparatus, and points rather to the latter when
automatism is desired. In the early days of the industry it would have
been impossible to speak so favourably of automatic carbide-to-water
generators, for they were at first constructed with absurdly complicated
and unreliable mechanism; but now various carbide-feed gears have been
devised which seem to be trustworthy even when carbide not in cartridge
form is employed.
NON-AUTOMATIC CARBIDE-TO-WATER GENERATORS.--There is little to be said in
the present place about the principles underlying the construction of
non-automatic generators. Such apparatus may either be of the carbide-to-
water or the water-to-carbide type. In the former, lumps of carbide are
dropped by hand down a vertical or sloping pipe or shoot, which opens at
its lower end below the water-level of the generating chamber, and which
is fitted below its mouth with a deflector to prevent the carbide from
lodging immediately underneath that mouth. The carbide falls through the
water which stands in the shoot itself almost instantaneously, but during
its momentary descent a small quantity of gas is evolved, which produces
an unpleasant odour unless a ventilating hood is fixed above the upper
end of the tube. As the ratio of cubical contents to superficial area of
a lump is greater as the lump itself is larger, and as only the outer
surface of the lump can be attacked by the water in the shoot during its
descent, carbide for a hand-fed carbide-to-water generator should be in
fairly large masses--granulated material being wholly unsuitable--and
this quite apart from the fact that large carbide is superior to small in
gas-making capacity, inasmuch as it has not suffered the inevitable
slight deterioration while being crushed and graded to size. If carbide
is dropped too rapidly into such a generator which is not provided with a
false bottom or grid for the lumps to rest upon, the solid is apt to
descend among a mass of thick lime sludge produced at a former operation,
which lies at the bottom of the decomposing chamber; and here it may be
protected from the cooling action of fresh water to such an extent that
its surface is baked or coated with a hard layer of lime, while
overheating to a degree far exceeding the boiling-point of water may
occur locally.
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