Acids, Alkalis and SaltsAdlam, George Henry Joseph
Science
Acids, Alkalis and Salts
Adlam, George Henry Joseph
Acids; Alkalies; Salts
Iron pyrites contains about 53 per cent. of sulphur combined with 47 per
cent. of iron, and when this is burnt in a good draught, nearly the
whole of the sulphur burns to sulphur dioxide, leaving a residue of
oxide of iron which can be used for making cast iron of a low grade.
Iron pyrites is often supplemented by the “spent oxide” from the gas
works. Crude coal gas contains sulphur compounds which, if not removed,
would burn with the gas and form sulphur dioxide. The production of
these pungent and suffocating fumes would be a source of great
annoyance, and therefore it is necessary to remove the sulphur
compounds. To do this, the gas is passed through two purifiers, the
first containing slaked lime and the second ferric oxide, both in a
slightly moist condition. After being some time in use, the purifying
material loses its efficacy; the residue from the lime purifier is sold
as “gas lime,” but that from the ferric oxide purifier is exposed to the
air and so “revived.” At length, however, it becomes so charged with
sulphur that it is of no further use for its original work. It is then
passed on to the sulphuric acid maker.
Evolution of the Manufacturing Process. In dealing with the main
processes for the manufacture of acids and alkalis, reference will
frequently be made to the methods of bygone times. Although as an exact
science Chemistry is comparatively modern, as a branch of human
knowledge its history goes back to the dawn of intelligence in man. It
is agreed that the higher types of living things are more easily
understood when those of a simpler and more primitive character have
been studied. In like manner, the highly specialized industries of
modern times become more intelligible in the light of the efforts of
past generations to achieve the same object.
Basil Valentine, who lived in the fifteenth century, states that the
liquid which we now call sulphuric acid was in his day obtained by
heating a mixture of green vitriol and pebbles. Until quite recent
times, sulphuric acid of a special grade was made by precisely the same
method, except that the pebbles were dispensed with. In passing, we may
remark that the common name “vitriol,” or “oil of vitriol,” is accounted
for by this connection with green vitriol. The second method, quoted by
Basil Valentine, consisted of the ignition of a mixture of saltpetre and
sulphur in the presence of water. This is actually the modern lead
chamber process in embryo.
[Illustration: Fig. 2. PLAN OF SULPHURIC ACID WORKS]
Public-domain text, read in full here on John Shaqi.
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