Acids, Alkalis and SaltsAdlam, George Henry Joseph
Science
Acids, Alkalis and Salts
Adlam, George Henry Joseph
Acids; Alkalies; Salts
The principal reaction is carried out in a tower (Fig. 14 (1), _a_, _a_)
from 50 to 65 ft. in height and about 6 ft. in diameter. At intervals of
about 3½ ft. throughout its length, the tower is divided into sections
by pairs of transverse discs, one flat with a large central hole, and
one hemispherical and perforated with small holes (Fig. 14 (2)). The
discs are kept in position by a guide rod G. Fig. 14 (3) shows a better
arrangement of the guide rods. In modern works, the space between the
discs is kept cool by pipes conveying running water. The ammoniated
brine is led into the tower near its middle point. The carbon dioxide is
forced in at E in the lowest segment, and as it passes up the tower it
is broken up into small bubbles by the sieve plates. Sodium bicarbonate
separates out as a fine powder, which makes its way to the bottom of the
tower suspended in the liquid.
The perforated plates are necessary for the proper distribution of
carbon dioxide through the brine. They are, however, a source of
trouble, because the holes quickly become blocked up with sodium
bicarbonate, and every ten days or so it is necessary to empty the tower
and clean it out with steam or boiling water.
Recovery of Ammonia. The production of 1 ton of soda ash by the Solvay
process involves the use of a quantity of ammonia which costs about
eight times as much as the price realized by selling the soda. It is
evident that the success of the process as a commercial venture depends
largely on the completeness with which the ammonia can be recovered.
During the process, ammonia is converted into ammonium chloride, which
remains dissolved in the residual liquor. From this ammonia gas is set
free by adding quicklime and by blowing steam through the mixture. It is
now claimed that 99 per cent. of the ammonia used in one operation is
recovered.
Soda Ash. The bicarbonate of soda produced by the Solvay process is
moderately pure. For all ordinary purposes, it is only necessary to wash
it with cold water to remove unchanged salt, and after drying, it is
ready to be placed on the market if it is to be sold as bicarbonate. The
greater part of the Solvay product, however, is converted into soda ash
by the application of heat. If soda crystals are required, the soda ash
is dissolved in water and crystallized.
In many ways, the Solvay process compares very favourably with the older
method. It is an advantage to start with brine, for that is the form in
which salt is very often raised from the mines. The end product is
relatively pure; moreover, it is quite free from caustic soda, which for
some purposes for which soda ash is used is a great recommendation.
There is no unpleasant smelling alkali waste. On the other hand, the
efficiency of the Solvay process is not high, for only about one-third
of the salt used is converted into soda. This would make the process
impossible from the commercial point of view were it not for the
cheapness of salt.
Public-domain text, read in full here on John Shaqi.
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