Varnishes may be divided into two classes--those in which the film
solidifies or “dries” by absorption of oxygen from the air, and
those in which the varnish “sets” by the evaporation of a volatile
solvent in which the solid ingredients have been dissolved. To
the first class belong the drying oils, chiefly linseed oil, for,
although there are a number of “drying” oils, but two or three
of them are used commercially in the manufacture of varnishes.
When exposed to the air, especially in warm weather, linseed oil
absorbs oxygen and forms an elastic translucent mass termed by
Mulder “linoxyn.” This linoxyn has completely lost its oily nature,
does not soil the fingers, and is, next to india-rubber, one of
the most elastic substances known. It possesses but little tensile
strength, however, and can be crumbled between the fingers. It
forms the basis of all linseed oil paint films, and is largely
used in the manufacture of linoleum. Linoxyn, however, is not, as
Mulder supposed, the final product of the oxidation of linseed oil.
When exposed to the air it is still further oxidised, and then
forms a sticky, viscid mass, of the consistency of treacle and of
an acid reaction. This latter property is of importance because
it is due to it that fabrics impregnated with linseed oil so soon
become rotten. In order to hasten the oxidation of linseed oil it
is usually heated with a small quantity of a lead or manganese
compound, and is then ready for use. No method of preparation can
prevent the super-oxidation of linseed oil, but experience has
indicated two ways of diminishing the evil effects so far as paints
and varnishes are concerned. The first is to mix the oil with
substances of a basic character or with which the acid product of
oxidation can combine. In the case of paints, white lead or zinc
oxide are chiefly used for this purpose. The other method consists
in mixing with the oil a gum resin which renders the film harder
and prevents liquefaction. Such a mixture of linseed oil and Kauri
gum forms an elastic, tough mass, which is much more durable than
the linoxyn alone, and also possesses greater tensile strength.
During oxidation the linseed oil absorbs about 12 per cent. of
its weight of oxygen, and when the area exposed is very large in
proportion to the weight of the oil the temperature may rise until
the mass catches fire. At a high temperature the super-oxidation
of the oil takes place more rapidly than in the winter, and I have
seen fabrics that had only been impregnated with an oil varnish
for a month cemented together in one sticky mass, and, of course,
completely ruined. When the linseed oil is thickened by the
addition of a gum resin, it is too thick for direct application,
and is thinned down with a solvent, usually turpentine or a mixture
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