of this with light petroleum. Many resins and gum resins are used
in the manufacture of varnishes in conjunction with linseed oil,
but none of them can deprive the oil of the defect referred to,
and if used in too large a proportion they become too brittle for
balloon purposes. Both scientific investigation and practical
experience show that any varnish containing linseed oil must be
looked upon with suspicion by the aëronaut, in spite of the glowing
testimonials some manufacturers are always ready to give their own
goods.
When we consider those varnishes which are solutions and which do
not depend upon oxidation for their drying properties we enter upon
a very wide field.
Practically any substance that is soluble in a neutral solvent and
leaves an impermeable film on drying is included in this class. One
of the simplest examples is gelatine in its various forms, with
water as a solvent. Until recently glue or gelatine would have
been useless for our purpose on account of its ready solubility
in water, but now that we are able to render it insoluble by
means of chromic acid or formaldehyde it comes within the limits
of practical applicability. A fabric may be rendered almost
impermeable to gas when coated on the inside with insoluble
gelatine, and on the outside with a waterproof varnish. Animal
membranes are far less permeable to gases than fabrics coated with
varnishes of the usual kinds. A balloon of gold-beaters’ skin, if
carefully constructed, will retain hydrogen gas for a long time,
and if treated with gelatine that is afterwards rendered insoluble
it becomes practically impermeable. Fabrics treated with linseed
oil varnish, on the other hand, allow gas to pass with comparative
ease. This is not a question of porosity or “pinholes,” as is
sometimes imagined, but a property inherent to the material.
Hydrogen or coal gas is absorbed on the one side of the film and
given off on the other in the same way as carbonic oxide will
pass through cast iron. An inert gas, such as nitrogen, does not
appear to diffuse in this way, even when there is a considerable
difference in pressure between the two sides of the film. Such a
varnished fabric transmits hydrogen readily, but retains nitrogen,
and is perfectly watertight. In filling up the interstices of a
fabric composed of cellulose the most obvious substance to use
would be cellulose itself, but until recently solutions of this
kind were difficult to obtain. Toy balloons have long been made
of collodion, and are fairly satisfactory, but a cotton fabric
impregnated with pure collodion becomes hard and even brittle.
Celluloid solution, which is collodion with camphor and a small
quantity of castor oil, is more flexible, but, probably on account
of the camphor, is more permeable to hydrogen than collodion. A
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