An Elementary Study of ChemistryMcPherson, William
Science
An Elementary Study of Chemistry
McPherson, William
Chemistry
That the gas obtained is different from air and oxygen may be
shown by holding a bottle of it mouth downward and bringing a
lighted splint into it. The hydrogen is ignited and burns with
an almost colorless flame.
[Illustration Fig. 9]
~Preparation from acids~ (_usual laboratory method_). While hydrogen can
be prepared from water, either by the action of the electric current or
by the action of certain metals, these methods are not economical and
are therefore but little used. In the laboratory hydrogen is generally
prepared from compounds known as acids, all of which contain hydrogen.
When acids are brought in contact with certain metals, the metals
dissolve and set free the hydrogen of the acid. Although this reaction
is a quite general one, it has been found most convenient in preparing
hydrogen by this method to use either zinc or iron as the metal and
either hydrochloric or sulphuric acid as the acid. Hydrochloric acid is
a compound consisting of 2.77% hydrogen and 97.23% chlorine, while
sulphuric acid consists of 2.05% hydrogen, 32.70% sulphur, and 65.25%
oxygen.
The changes which take place in the preparation of hydrogen from zinc
and sulphuric acid (diluted with water) may be represented as follows:
_ _ _ _
| hydrogen |(sulphuric | zinc |(zinc
zinc + | sulphur | acid) = | sulphur | sulphate) + hydrogen
|_oxygen _| |_oxygen _|
In other words, the zinc has taken the place of the hydrogen in
sulphuric acid. The resulting compound contains zinc, sulphur, and
oxygen, and is known as zinc sulphate. This remains dissolved in the
water present in the acid. It may be obtained in the form of a white
solid by evaporating the liquid left after the metal has passed into
solution.
When zinc and hydrochloric acid are used the following changes take
place:
_ _ _ _
| hydrogen |(hydrochloric | zinc |(zinc
zinc + |_chlorine_| acid) = |_chlorine_| chloride) + hydrogen
When iron is used the changes which take place are exactly similar to
those just given for zinc.
[Illustration Fig. 10.]
~Directions for preparing hydrogen from acids.~ The preparation
of hydrogen from acids is carried out in the laboratory as
follows: The metal is placed in a flask or wide-mouthed bottle
A (Fig. 10) and the acid is added slowly through the funnel
tube B. The metal dissolves in the acid, while the hydrogen
which is liberated escapes through the exit tube C and is
collected over water. It is evident that the hydrogen which
passes over first is mixed with the air from the bottle A.
Hence care must be taken not to bring a flame near the exit
tube, since, as has been stated previously, such a mixture
explodes with great violence when brought in contact with a
flame.
Public-domain text, read in full here on John Shaqi.
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