An Elementary Study of ChemistryMcPherson, William
Science
An Elementary Study of Chemistry
McPherson, William
Chemistry
~Precautions.~ Both sulphuric acid and zinc, if impure, are
likely to contain small amounts of arsenic. Such materials
should not be used in preparing hydrogen, since the arsenic
present combines with a portion of the hydrogen to form a very
poisonous gas known as arsine. On the other hand, chemically
pure sulphuric acid, i.e. sulphuric acid that is entirely free
from impurities, will not act upon chemically pure zinc. The
reaction may be started, however, by the addition of a few
drops of a solution of copper sulphate or platinum
tetrachloride.
~Physical properties.~ Hydrogen is similar to oxygen in that it is a
colorless, tasteless, odorless gas. It is characterized by its extreme
lightness, being the lightest of all known substances. One liter of the
gas weighs only 0.08984 g. On comparing this weight with that of an
equal volume of oxygen, viz., 1.4285 g., the latter is found to be 15.88
times as heavy as hydrogen. Similarly, air is found to be 14.38 times as
heavy as hydrogen. Soap bubbles blown with hydrogen rapidly rise in the
air. On account of its lightness it is possible to pour it upward from
one bottle into another. Thus, if the bottle A (Fig. 11) is filled
with hydrogen, placed mouth downward by the side of bottle _B_, filled
with air, and is then gradually inverted under B as indicated in the
figure, the hydrogen will flow upward into bottle _B_, displacing the
air. Its presence in bottle B may then be shown by bringing a lighted
splint to the mouth of the bottle, when the hydrogen will be ignited by
the flame. It is evident, from this experiment, that in order to retain
the gas in an open bottle the bottle must be placed mouth downward.
[Illustration Fig. 11]
Hydrogen is far more difficult to liquefy than any other gas, with the
exception of helium, a rare element recently found to exist in the
atmosphere. The English scientist Dewar, however, in 1898 succeeded not
only in obtaining hydrogen in liquid state but also as a solid. Liquid
hydrogen is colorless and has a density of only 0.07. Its boiling point
under atmospheric pressure is -252 deg.. Under diminished pressure the
temperature has been reduced to -262 deg.. The solubility of hydrogen in
water is very slight, being still less than that of oxygen.
Pure hydrogen produces no injurious results when inhaled. Of course one
could not live in an atmosphere of the gas, since oxygen is essential to
respiration.
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