An Elementary Study of ChemistryMcPherson, William
Science
An Elementary Study of Chemistry
McPherson, William
Chemistry
~Chemical properties.~ At ordinary temperatures hydrogen is not an active
element. A mixture of hydrogen and chlorine, however, will combine with
explosive violence at ordinary temperature if exposed to the sunlight.
The union can be brought about also by heating. The product formed in
either case is hydrochloric acid. Under suitable conditions hydrogen
combines with nitrogen to form ammonia, and with sulphur to form the
foul-smelling gas, hydrogen sulphide. The affinity of hydrogen for
oxygen is so great that a mixture of hydrogen and oxygen or hydrogen
and air explodes with great violence when heated to the kindling
temperature (about 612 deg.). Nevertheless under proper conditions hydrogen
may be made to burn quietly in either oxygen or air. The resulting
hydrogen flame is almost colorless and is very hot. The combustion of
the hydrogen is, of course, due to its union with oxygen. The product of
the combustion is therefore a compound of hydrogen and oxygen. That this
compound is water may be shown easily by experiment.
[Illustration Fig. 12]
~Directions for burning hydrogen in air.~ The combustion of
hydrogen in air may be carried out safely as follows: The
hydrogen is generated in the bottle A (Fig. 12), is dried by
conducting it through the tube X, filled with some substance
(generally calcium chloride) which has a great attraction for
moisture, and escapes through the tube T, the end of which is
drawn out to a jet. The hydrogen first liberated mixes with the
air contained in the generator. If a flame is brought near the
jet before this mixture has all escaped, a violent and very
dangerous explosion results, since the entire apparatus is
filled with the explosive mixture. On the other hand, if the
flame is not applied until all the air has been expelled, the
hydrogen is ignited and burns quietly, since only the small
amount of it which escapes from the jet can come in contact
with the oxygen of the air at any one time. By holding a cold,
dry bell jar or bottle over the flame, in the manner shown in
the figure, the steam formed by the combustion of the hydrogen
is condensed, the water collecting in drops on the sides of the
jar.
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