An Elementary Study of ChemistryMcPherson, William
Science
An Elementary Study of Chemistry
McPherson, William
Chemistry
The 20.3 cc. of hydrogen have combined with 18.4 cc. minus 8.3 cc. (or
10.1 cc.) of oxygen; or approximately 2 volumes of hydrogen have
combined with 1 of oxygen. Since oxygen is 15.88 times as heavy as
hydrogen, the proportion by weight in which the two gases combine is 1
part of hydrogen to 7.94 of oxygen.
~Precaution.~ If the two gases are introduced into the eudiometer in the
exact proportions in which they combine, after the combination has taken
place the liquid will rise and completely fill the tube. Under these
conditions, however, the tube is very likely to be broken by the sudden
upward rush of the liquid. Hence in performing the experiment care is
taken to introduce an excess of one of the gases.
~A more convenient form of eudiometer.~ A form of eudiometer (Fig. 21)
different from that shown on page 43 is sometimes used to avoid the
calculations necessary in reducing the volumes of the gases to the same
conditions of temperature and pressure in order to make comparisons.
With this apparatus it is possible to take the readings of the volumes
under the same conditions of temperature and pressure, and thus compare
them directly. The apparatus (Fig. 21) is filled with mercury and the
gases introduced into the tube A. The experiment is carried out as in
the preceding one, except that before taking the reading of the gas
volumes, mercury is either added to the tube B or withdrawn from it by
means of the stopcock C, until it stands at exactly the same height in
both tubes. The gas inclosed in tube A is then under atmospheric
pressure; and since but a few minutes are required for performing the
experiment, the conditions of temperature and pressure may be regarded
as constant. Hence the volumes of the hydrogen and oxygen and of the
residual gas may be read off from the tube and directly compared.
[Illustration: Fig. 21]
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