An Elementary Study of ChemistryMcPherson, William
Science
An Elementary Study of Chemistry
McPherson, William
Chemistry
~Method used by Berzelius and Dumas.~ The method used by these
investigators enables us to determine directly the proportion by weight
in which the hydrogen and oxygen combine. Fig. 22 illustrates the
apparatus used in making this determination. B is a glass tube
containing copper oxide. C and D are glass tubes filled with calcium
chloride, a substance which has great affinity for water. The tubes B
and C, including their contents, are carefully weighed, and the
apparatus connected as shown in the figure. A slow current of pure
hydrogen is then passed through A, and that part of the tube B which
contains copper oxide is carefully heated. The hydrogen combines with
the oxygen present in the copper oxide to form water, which is absorbed
by the calcium chloride in tube C. The calcium chloride in tube D
prevents any moisture entering tube C from the air. The operation is
continued until an appreciable amount of water has been formed. The
tubes B and C are then weighed once more. The loss of weight in the
tube B will exactly equal the weight of oxygen taken up from the
copper oxide in the formation of the water. The gain in weight in the
tube C will exactly equal the weight of the water formed. The
difference in these weights will of course equal the weight of the
hydrogen present in the water formed.
[Illustration: Fig. 22]
~Dumas' results.~ The above method for the determination of the
composition of water was first used by Berzelius in 1820. The work was
repeated in 1843 by Dumas, the average of whose results is as follows:
Weight of water formed 236.36 g.
Oxygen given up by the copper oxide 210.04
------
Weight of hydrogen present in water 26.32
According to this experiment the ratio of hydrogen to oxygen in water is
therefore 26.32 to 210.04, or as l to 7.98
~Morley's results.~ The American chemist Morley has recently determined
the composition of water, extreme precautions being taken to use pure
materials and to eliminate all sources of error. The hydrogen and oxygen
which combined, as well as the water formed, were all accurately
weighed. According to Morley's results, 1 part of hydrogen by weight
combines with 7.94 parts of oxygen to form water.
~Comparison of results obtained.~ From the above discussions it is easy to
see that it is by experiment alone that the composition of a compound
can be determined. Different methods may lead to slightly different
results. The more accurate the method chosen and the greater the skill
with which the experiment is carried out, the more accurate will be the
results. It is generally conceded by chemists that the results obtained
by Morley in reference to the composition of water are the most accurate
ones. In accordance with these results, then, _water must be regarded as
a compound containing hydrogen and oxygen in the proportion of 1 part by
weight of hydrogen to 7.94 parts by weight of oxygen_.
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