An Introduction to Chemical ScienceWilliams, Rufus P. (Rufus Phillips)
Science
An Introduction to Chemical Science
Williams, Rufus P. (Rufus Phillips)
Chemistry
Suppose we wish to know the symbol for calcium phosphate. Ca and
PO4 are the two parts. In H3(PO4) the radical is a triad, to
balance H3. Ca is a dyad, Ca==(P04). The least common multiple of
the bonds (2 and 3) is 6, which, divided by 2 (no. Ca bonds),
gives 3 (no. Ca atoms to be taken). 6 / 3 (no. (PO4) bonds) gives
2 (no. PO4 radicals to be taken). Hence the symbol Ca3(P04)2.
Verify this by writing graphically.
Write symbols for the union of Mg and (SO4), Na and (PO4), Zn and
(NO3), K and (NO3), K and (SO4), Mg and (PO4), Fe and (SO4) (both
valences of Fe), Fe and (NO3), taking the valences of the
radicals from HNO3, H2SO4, H3PO4.
Chapter XII.
ELECTRO-CHEMICAL RELATION OF ELEMENTS.
58. Examine untarnished pieces of iron, silver, nickel, lead,
etc.; also quartz, resin, silk, wood, paper. Notice that from the
first four light is reflected in a different way from that of the
others. This property of reflecting light is known as luster.
Metals have a metallic luster which is peculiar to themselves;
and this, for the present, may be regarded as their chief
characteristic. Are they at the positive or negative end of the
list? See page 43. How is it with the non-metals? This
arrangement has a significance in chemistry which we must now
examine. The three appended experiments show how one metal can be
withdrawn from solution by a second, this second by a third, the
third by a fourth, and so on. For expedition, three pupils can
work together for the three following experiments, each doing
one, and examining the results of the others.
59. Deposition of Silver.
Experiment 35.--Put a ten-cent Ag coin into an evaporating-dish,
and pour over it a mixture of 5 cc. HNO3 and 10 cc. H2O. Warm
till all, or nearly all, the Ag dissolves. Remove the lamp. 3 Ag
+ 4 HNO3 = 3 AgNO3 + 2 H2O + NO. Then add 10 cc. H2O, and at once
put in a short piece of Cu wire, or a cent. Leave till quite a
deposit appears, then pour off the liquid, wash the deposit
thoroughly, and remove it from the coin. See whether the metal
resembles Ag. 2 AgNO3 + Cu =?60. Deposition of Copper.
Experiment 36.--Dissolve a cent or some Cu turnings in dilute
HNO3, as in Experiment 35, and dilute the solution. 3 Cu + 8 HN09
- 3 Cu (NOA+4 H2O+2 NO.)
Then put in a clean strip of Pb, and set aside as before,
examining the deposit finally. Cu(NO3), + Pb - ?
61. Deposition of Lead.
Experiment 37.--Perform this experiment in the same manner as the
two previous ones, dissolving a small piece of Pb, and using a
strip of Zn to precipitate the Pb. 3 Pb + 8 HNO3 - 3 Pb (NO4)2 +
4 Ha0 + 2 NO. Pb (NO3) 2 + Zn = ? h.
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