An Introduction to Chemical ScienceWilliams, Rufus P. (Rufus Phillips)
Science
An Introduction to Chemical Science
Williams, Rufus P. (Rufus Phillips)
Chemistry
62. Explanation. -These experiments show that Cu will replace Ag
in a solution of AgNO3, that Pb will replace and deposit Cu from
a similar compound, and that Zn will deposit Pb in the same way.
They show that the affinity of Zn for (NO3) is stronger than
either Ag, Cu, or Pb. We. express this affinity by saying that Zn
is the most positive of the four metals, while Ag is the most
nega- tive. Cu is positive to Ag, but negative to Pb and Zn.
Which of the four elements are positive to Pb, and which
negative? Mg would withdraw Zn from a similar solution, and be in
its turn withdrawn by Na. The table on page 43 is founded on this
relation. A given element is positive to every element above it
in the list, and negative to all below it.
Metals are usually classed as positive, non-metals as negative.
Each in union with O and 1=I gives rise to a very important class
of compounds,=--the negative to acids, the positive to bases.
In the following, note whether the positive or the negative
element is written first:--HCl, Na20,-As2S3, -MgBr2, Ag2S. Na2SO4
is made up of two parts, Na2 being positive, the radical SO4
negative. Like elements, radicals are either positive or
negative. In the following, separate the positive element from
the negative radical by a vertical line: Na2CO3, NaNO3, ZnSO4,
KClO3.
The most common positive radical is NH4, ammonium, as in NH4Cl.
It always deports itself as a metal. The commonest radical is the
negative OH, called hydroxyl, from hydrogen- oxygen. Take away H
from the symbol of water, H-O-H, and hydroxyl --(OH) with one
free bond is left. If an element takes the place of H, i.e.
unites with OH, the compound is called a hydrate. KOH is
potassium hydrate. Name NaOH, Ca(OH)2, NH4OH, Zn(OH)2, Al2(OH)6.
Is the first part of each symbol above positive or negative?
H has an intermediate place in the list. It is a constituent of
both acids and bases, and of the neutral substance, water.
ORDER.
--
Negative or Non-Metallic Elements.
Acid-forming with H(usually OH).
Oxygen
Sulphur
Nitrogen
Fluorine
Chlorine
Bromine
Iodine
Phosphorus
Arsenic
Carbon
Silicon
Hydrogen
Positive or Metallic Elements.
Base-forming with OH.
Gold
Platinum
Mercury
Silver
Copper
Tin
Lead
Iron
Zinc
Aluminium
Magnesium
Calcium
Sodium
Potassium
CHAPTER XIII.
ELECTROLYSIS.
The following experiment is to be performed only by the teacher,
but pupils should make drawings and explain.
63. Decomposition of Water.
Public-domain text, read in full here on John Shaqi.
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