An Introductory Course of Quantitative Chemical Analysis: With Explanatory NotesTalbot, Henry Paul
Science
An Introductory Course of Quantitative Chemical Analysis: With Explanatory Notes
Talbot, Henry Paul
Chemistry, Analytic -- Quantitative
An exactly opposite result follows the solution of such a salt as
Al_{2}(SO_{4})_{3} in water. In this case the acid is strong and the
base weak, and the OH^{-} ions form the little dissociated Al(OH)_{3},
while the H^{+} ions remain as such in the solution, sulphuric acid
being extensively dissociated. The solution exhibits an acid reaction.
Such hydrolytic processes as the above are of great importance in
analytical chemistry, especially in the understanding of the action of
indicators in volumetric analysis. (See page 32.)
The impelling force which causes an element to pass from the atomic
to the ionic condition is termed !electrolytic solution pressure!, or
ionization tension. This force may be measured in terms of electrical
potential, and the table below shows the relative values for a number
of elements.
In general, an element with a greater solution pressure tends to cause
the deposition of an element of less solution pressure when placed in
a solution of its salt, as, for instance, when a strip of zinc or
iron is placed in a solution of a copper salt, with the resulting
precipitation of metallic copper.
Hydrogen is included in the table, and its position should be noted
with reference to the other common elements. For a more extended
discussion of this topic the student should refer to other treatises.
POTENTIAL SERIES OF THE METALS
__________________________________________________________________
| | |
| POTENTIAL | | POTENTIAL
| IN VOLTS | | IN VOLTS
_____________________|___________|____________________|___________
| | |
Sodium Na^{+} | +2.44 | Lead Pb^{++} | -0.13
Calcium Ca^{++} | | Hydrogen H^{+} | -0.28
Magnesium Mg^{++} | | Bismuth Bi^{+++}|
Aluminum A1^{+++} | +1.00 | Antimony | -0.75
Manganese Mn^{++} | | Arsenic |
Zinc Zn^{++} | +0.49 | Copper Cu^{++} | -0.61
Cadmium Cd^{++} | +0.14 | Mercury Hg^{+} | -1.03
Iron Fe^{++} | +0.063 | Silver Ag^{+} | -1.05
Cobalt Co^{++} | -0.045 | Platinum |
Nickel Ni^{++} | -0.049 | Gold |
Tin Sn^{++} | -0.085(?) | |
_____________________|___________|____________________|__________
THE FOLDING OF A FILTER PAPER
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