Now in a gelatine sol we have the necessary conditions for a system in
which the compressed water bears an unusually large ratio to the total,
owing to the enormous surface developed by the minute particles of the
disperse phase (amicrons) and to the unusually wide zone of compression
surrounding each particle caused by the strongly hydrophile nature of
gelatine. It should be pointed out that these zones of compression do
not involve any abrupt transition from the zone of non-compression, the
layer nearest the particle is under the greatest pressure, and the
concentric layers under less and less pressures, the actual compression
being thus an inverse function of the distance from the particle. Now if
there be a gradual increase in the concentration of the sol, the time
will come when these zones of compression begin to come in contact, and
the system will then show a considerably increased viscosity. With
further increase in concentration the zones of compression will overlap
throughout the system, and when the layers under considerable pressure
are thus continuous, the whole system will acquire a rigidity much
greater than water and approaching that of a solid body. This is a
gelatine gel, or "jelly." With increasing concentration the jelly
becomes increasingly rigid, and if it be eventually dried out under
suitable conditions it forms what is practically solid
body--gelatine--which, however, still contains from 12 to 18 per cent.
of water.
It will be clear that, in the case of gelatine jellies (_e.g._ of 3-10
per cent. strength), an increase in temperature will cause an increase
in the kinetic energy of the particles and effectively reduce the zones
of compression. Indeed, they may be reduced to such an extent that they
are no longer in contact, and the rigidity due to the continuous contact
of the layers of great compression will then disappear; as we say
usually, the jelly melts. On cooling, the decreased kinetic energy of
the water molecules results in the return of the state of compression,
with rapidly increasing viscosity and eventual gelation; as we say
usually, the jelly sets. Neither of these changes takes place at a
definite temperature (like a melting-point), and in "melting" (solation)
or in "setting" (gelation) the temperature-viscosity curve is quite
continuous. By various arbitrary devices, however, approximate melting
and setting points may approximately be determined. The results also
vary somewhat with the concentration of the gel or sol. Gels between 5
and 15 per cent. strong melt about 26°-30° C. and set at 18°-26° C.
On this view, we must regard a gelatine gel as a continuous network of
water under great compression, and in this network are zones of still
greater compression, which surround the particles of the disperse
phase--the gelatine itself, and zones of less compression which in a
weak gel, at any rate, have a compression equal to or much the same as
the normal state of compression in water.
Public-domain text, read in full here on John Shaqi.
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