The chief principle of extraction is so to arrange the process that both
the material and the extracted liquor are maintained at high
temperatures for the shortest possible time. As we have observed,
gelatine is readily hydrolyzed by hot water, and as hot water is needed
for its extraction or solution, care must be taken to remove the
solution as soon as possible from the source of heat. In practice this
can only be done somewhat imperfectly, as it is necessary to obtain a
gelatine sol of several per cent. strength before removing it from the
extraction vessel. The stronger this sol is made before removal, the
less the time, trouble and expense is incurred in evaporation
subsequently, but the more is the exposure to heat with consequent
weakening of the gelatine. Hence in practice it is necessary to
compromise. The matter is complicated further by the necessity of
obtaining a clear sol, for which it is desirable that the sol obtained
in extraction should not be too concentrated, as impurities settle and
filter much more readily from weaker and less viscous sols.
It will be understood, therefore, that whatever material is being
extracted, the most favoured procedure is to extract in fractions. The
first fraction, which is least exposed to hydrolytic decomposition,
produces the highest quality products, and the subsequent fractions
(nearly always two more, and sometimes several) yield products which
gradually become of inferior quality owing to the number of times the
raw material has been re-heated.
Within limits, the precise temperature of extraction does not have the
importance one would expect. Lambert suggests the temperature of 185° F.
as suitable for both skin and bone gelatine, and most manufacturers
would, on the whole, endorse this. If, however, a higher temperature be
preferred, the hydrolytic action is increased in intensity but decreased
in its time of operation, whilst if a lower temperature be adopted the
decomposition is retarded in speed, but is increased in totality because
of the longer time needed to obtain a suitable strength of liquor. Thus,
with care, much the same result is obtained by extraction at near
boiling-point for a short time as by extraction at 160° F. for a long
time. The higher temperatures have the definite advantage of speed,
whilst the lower temperatures have the advantage that one may choose to
be satisfied with a weaker extract, and so gain a little in the strength
of the gel, by throwing more work on the evaporator. One other point
should, however, be borne in mind in this connection, viz. that a
gelatine sol kept at temperatures above 185° F. begins to deteriorate in
colour. Whilst, therefore, much depends upon the precise class of
material, it is broadly true to say that the higher temperatures are
advantageous for glue, whilst the lower temperatures are preferable for
the highest quality gelatine.
Public-domain text, read in full here on John Shaqi.
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