=Bleaching by Oxidation.=--Many oxidizing agents have been suggested for
bleaching gelatine, but most of them have some practical disadvantage.
Most of them contradict the maxim (previously noted) that it is
desirable to avoid adding any soluble substance, as this involves a
permanent impurity, possibly concentrated to supersaturation in the
finishing processes, and possibly involving a disadvantageous lyotrope
influence. There is another objection to oxidizing agents also; whilst
their bleaching action on the pigments is undoubted, some of them have
also a special action upon the gelatine itself which is in reality akin
to tanning, and may indeed involve an insolubilization of the gelatine.
Thus, chlorine gas (which Meunier patented for tanning) has been used
for bleaching gelatine, but the conditions of success have not yet been
thoroughly elucidated, and it is problematical indeed whether the
process is consistent with best results. Hypochlorites and bleaching
powder have also a similar action, which has been utilized with some
success in practice. Rideal suggests that a suitable concentration for
these reagents is 1:2000, and emphasizes the care necessary. An
advantage of all these chlorinations is the formation of the strongly
antiseptic chloramines, which preserve the gelatine from putrefaction.
Ozone has also been tried as an oxidation bleach for gelatine, but not
successfully, partly on account of difficulties in controlling the
quantity used. Peroxide of soda has also been used, but it is not only
alkaline, but liable to contain sodium hydrate and carbonate as
impurities, and this involves neutralization either before use or in the
gelatine sol, and the consequent presence of sodium salts in the
finished article. Peroxide of calcium is open to the same objections,
except that calcium is more easily removed from the sol than sodium.
Rideal's suggestion for removing this lime, viz. precipitation by a
current of carbonic acid, merits attention in this and in other
directions also. Rideal also states that in the case of an acid bone
gelatine, a good peroxide of lime is almost an ideal reagent for
bleaching, inasmuch as "the lime carries down phosphate, several
impurities and colouring matters." It thus acts as bleach, as
neutralizing agent, and as precipitant, and the precipitate itself is a
strong adsorbent. On account of its freedom from bases, and because its
residue is simply water, peroxide of hydrogen has been found of great
service in practice, and in most factories it has shown itself superior
not only to the other peroxides, but also to all other oxidizing
agents. Its application is simple, a concentrated solution being added
to the gelatine sol before or after evaporation. It is the most
"fool-proof" of all the oxidizing agents used in bleaching, and it
yields the purest product. Its bleaching action is perfectly
satisfactory, but only in a non-acid sol. Hydrogen peroxide is
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