moderately stable in acid solution, and its bleaching action is best in
slightly alkaline solution. An acid sol bleaches too slowly, or not at
all; an alkaline sol induces evolution of oxygen and consequent waste.
The great disadvantage of peroxide of hydrogen is its great expense,
which is enhanced by an increasing demand for it in other industries. A
minor disadvantage is its instability, which leads to loss in transit
and storage. It is sold usually in strengths indicated by the volume of
oxygen obtained from unit volume of the solution, when treated with
permanganate in a nitrometer (_e.g._ "15 vols. peroxide").
It is a fortunate feature of both the oxidizing and reducing agents
usually employed in bleaching, that they have considerable antiseptic
power. This assists materially in preserving the gelatine from
putrefaction during the critical period between extraction and
concentration.
REFERENCES.
"Glue and Glue Testing," S. Rideal, D.Sc., 2nd ed., pp. 61-66,
78-82.
"Gelatine, Glue, and Allied Products," T. Lambert, pp. 29, 30, 49,
51.
"Chemical Engineering," _J.R. San. Inst._, No. 2, 1910. S. Rideal.
On adsorption phenomena:
1. "Chemistry of Colloids," Dr. W. W. Taylor.
2. "Chemistry of Colloids," V. Pöschl.
3. "Chemistry of Colloids," Zsigmondy and Spear.
4. "Chemistry and Physics of Colloids," E. Halschek.
5. "Surface Tension and Surface Energy," Willows and Hatschek.
SECTION VI.--EVAPORATION
The evaporation of the weak gelatine sols (3-9 per cent.) obtained by
the processes described in previous sections into sols of such
concentration (20-55 per cent.) that they readily set to a stiff gel on
cooling, is now an essential feature of gelatine manufacture, and is one
of the most important processes.
In the early days of this industry, manufacturers aimed at obtaining a
concentrated sol, as this saved time in drying, and so reduced the
possibilities of putrefaction. The advent of evaporation has reduced
these possibilities to a minimum, and has also enormously reduced the
space required and the capital outlay needed in the drying sheds. It
has, in addition, given the practical advantages involved in dealing up
to the last minute with a much less viscous liquor. As the liquors
extracted are weaker, the extraction is more complete and the
decolorization more easily effected.
The earliest attempts at evaporation were not very successful, partly on
account of the prolonged "stewing" which ruined the setting power, and
partly because of the poor economy of heat. Thus in the open evaporators
the sol was maintained at a high temperature for a long period, and this
process only proved suitable for low-grade products.
Public-domain text, read in full here on John Shaqi.
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