Innumerable "artificial" bates have
been put on the market, but most are merely weak acids, acid salts or
salts of strong acids with weak bases. An American "bacterial bate"
consists of a lactic fermentation of glucose in the presence of glue.
Closely similar to bating is "puering," investigated by Wood.
Drenching is another fermentive deliming process. In this the goods are
inserted into an infusion of bran. This is made by scalding the bran
with hot water, and allowing it to stand until it is about 70°-90° F.
The infusion is then "inoculated" with a few gallons of old drench
liquor, and the goods are immersed. This fermentation has been examined
carefully by J. T. Wood. First the enzyme cerealin converts bran starch
into glucose, which is then fermented by the drench bacteria with the
production of lactic acid, some acetic acid and small amounts of formic
and butyric acids. The butyric fermentation is liable to become too
violent. These acids, as they are formed, neutralize the lime in the
hides and plump the pelt slightly.
Various gases (carbon dioxide, hydrogen, nitrogen, methane and
sulphuretted hydrogen) are involved, and the proportion produced in the
pelt itself has a peculiar opening effect on the hide fibres. The
activity of the drench can be decreased by dilution and by using a less
starchy bran, and can be increased by adding pea meal or rye meal.
Drenching usually follows bating. Scudding sometimes follows deliming.
The theory of the volume and elasticity changes of pelt during
preparation will be better understood after considering the behaviour of
gelatine gels. The determining factors are the _nett_
charge of hydroxyl ions on the disperse phase, resulting from ionic
adsorptions, and the lyotrope influence of dissolved substances on the
continuous phase.
In softening dried hides the swelling may be due to either influence,
but the latter tends to loss of hide substance and the production of
soft leather.
In liming, the nett adsorption of hydroxyl ions is the principal factor,
but the lyotrope influence of the alkali cations and of the impurities
is important. Plump pelts are those in which the contained water is in a
relatively greater average state of compression. Few substances can
assist plumping, but many can hinder it. In plumping all lyotrope
influence is objectionable, and "sharp" (pure) alkali solutions are
required. Mellow limes reduce elasticity and plumpness by lyotrope
influence.
In bating and puering the essential change is that before the process
the swelling is due chiefly to adsorption of hydroxyl ions, whereas
afterwards it is due chiefly to a composite lyotrope influence.
REFERENCES.
"Principles of Leather Manufacture," Procter, pp. 108-184.
"The Manufacture of Leather," Bennett, pp. 49-113.
"Lyotrope Influence and Adsorption in the Theory of Wetwork,"
Bennett, _J.S.L.T.C._, 1920, pp. 75-86.
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