=Deliming= is a general name covering a number of similar operations
whose primary object is the neutralization and removal of the caustic
lime and soda in the plumped pelt, or at any rate on the surface of the
hide. This is a preparation for the tan liquors. All the tannins and
many associated substances darken rapidly with oxidation when in
alkaline solution, so that to place the fully limed hide in a tan liquor
would give a dark-coloured leather. A short insertion in a bath of weak
acid would secure the elimination of surface lime and the disappearance
of this difficulty, but there are other purposes in deliming. The more
completely lime is removed the more the plumped pelt "falls" into a
soft, pliable, unswollen and relaxed condition, and this change assists
very materially in the production of a soft dressing leather, suitable
for boot uppers, bags, etc. For such leathers, therefore, the deliming
must be much more complete than for sole leather, in which the object is
to obtain a firm and plump leather.
In the case of the softer dressing leathers, experience indicates the
advisability of allowing some further bacterial action on the
interfibrillar substance in order to produce the requisite pliability
and softness. This is secured by "bating" the hides. This process
consists in immersing the goods into a cold fermenting infusion of hen
or pigeon dung. The infusion is made in a special tub or pit with warm
water and allowed to stand for a day or two until the fermentation has
commenced, and then run into the bating pit through a coarse filter such
as sacking. The hides are immersed for some days, but are handled
frequently to ensure an even effect. The bate is always slightly
alkaline. The caustic alkalinity increases rapidly at first owing to the
diffusion of caustic lime, then at a slower rate, afterwards slowly
declining. This is explained by the production of organic acids, and
their salts with weak bases from the dung infusion by the action of
bacteria. The total alkalinity of the bate liquor increases rapidly at
first owing to the diffusion of lime and its liberation of organic
bases, then very slowly, but towards the end of the operation the total
alkalinity increases very rapidly indeed, owing probably to the
commencement of a violent anærobic fermentation which produces ammonia
and other organic bases, and which heralds the approach of a
putrefactive action, which if allowed to continue for even a short time
will ruin the hides. Bating is consequently a risky process, and needs
experienced oversight. For goods which need only a mild bating, there is
the alternative of giving a longer liming in older limes. This of course
involves more bacterial hydrolysis, and perhaps does it in a safer, more
economical and certainly in a less offensive manner. Bating is often
followed by a further deliming by acids. Boric, lactic, acetic, formic
and butyric acids are all used, and with care even hydrochloric and
sulphuric acids may be employed.
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