Mimosa bark is one of the most important catechol tans. It is usually
obtained in this country from Natal ("Natal bark"); but the tree (Sydney
green wattle, _Acacia mollissima_) is a native of Australia. It is being
cultivated now extensively in South Africa, and forms a most valuable
portion of the Empire's stock of tanning material. Its more extensive
use has been long recommended by the author,[4] but its gradually
increasing employment in British tanneries has been greatly accelerated
by the war, which has prevented its delivery in Germany and has cut off
Turkish valonia from Britain. It yields about 30 per cent. of a stable
and excellent tannin, and will produce a firm, durable leather, with a
colour much less red than that obtained from many other catechol tans.
It is an astringent tan, and if carelessly used yields a harsh or even
"drawn" grain. Most of the tannin is easily extracted, yielding a clear
infusion which penetrates fairly quickly and gives good weight. It
contains less than 1 per cent. of sugar, which unfortunately rapidly
ferments to carbonic acid, so that it is not a good plumping material.
It makes in all respects an excellent blend with myrabolans. Like all
catechol tans, the resulting leather darkens on exposure to sunlight.
[Footnote 4: J.S.C.I., 1908, 1193.]
Oak bark, from _Quercus robur_, is the ancient tanning material of
Britain, and is still used to a limited extent. It contains about 13 per
cent. of tannin and is mainly a catechol tan, but also contains a
pyrogallol derivative. It yields catechin, and gives a red colour with
the sodium arsenate test, but also will yield some bloom and gallic
acid, and gives a blue-black with ferric salts. The tannin itself is
exceedingly similar to that of mimosa bark, but the material contains
about 2-1/2 per cent. of sugar, which makes it possible to employ oak
bark alone for making sole leather. It is noted for yielding a sound,
durable leather of good typical tan colour. Its tannin combines well
with hide and penetrates quickly. The fatal disadvantage of oak bark is
its weakness in tannin strength compared with other materials. This
results in heavy freight and heavy cost per unit tannin, bulky storage,
expensive handling in the factory, comparatively large bulk of spent
tan, after relatively greater trouble in extracting, and the
impossibility of making the strong liquors so necessary in these days to
produce good weight in a short time. No satisfactory extract has yet
been made from it.
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