Pine bark, from _Pinas abies_, is one of the staple materials of the
Continent. It contains up to 14 per cent. of a catechol tan, and, unlike
most of this group, contains a high proportion of sugar and will give
good results alone. Hemlock bark has been the staple tanning material of
North America. It is obtained from the hemlock, or _Pinus canadensis_.
It contains up to 11 per cent. of tan and much phlobaphene, and yields a
characteristic red leather of good quality, but which rapidly darkens
with sunlight. It contains some sugar, but is usually employed in
conjunction with sulphuric acid or with sugary materials. Mallet bark
yields another catechol tan similar to that of mimosa, but somewhat less
astringent and more yellow in colour. Quebracho wood and mangrove bark
have been used, but are now made into extracts.
=Leaching.=--Whatever class of leather is being made, and whatever blend
of tanning materials is being employed, the tannins must be efficiently
extracted by water in order to make the tanning liquors. This process is
called "leaching." The tanning materials, after being ground, crushed or
shredded, are placed in large pits arranged in "rounds," "sets," or
"batteries" of 6, 8 or 10 units, through which water is percolated
systematically, so as to secure a continuous extraction. Water itself is
added to only one of the pits of material. The liquor produced is passed
on to the next pit, and then to the next, and is continually gathering
strength. After passing thus through the series, the liquor becomes the
source of the strong extracted tan liquors which are used in the tannery
proper. With this system the stronger leach liquors are being acted upon
by fresh material, and the nearly "spent" material is being acted on by
the weakest liquors, and finally by water, thus ensuring a complete
extraction. In the press leach system, which is now practically
universal, the bottom of one pit communicates with the top of the next,
and the liquor presses round by gravity flow caused by a few inches
"fall." Liquor is thus constantly percolating downward through the
material in each pit. The "head leach" and "tail leach" are always
adjacent in a double row of pits, and when the material in the latter is
quite spent, it is "cast," and the pit is filled with fresh material.
The liquor is then pressed round into this pit by adding water to the
tail leach. Hot water is used to secure better diffusion. At least two
such sets of leaches ("taps" and "spenders") are necessary to spend the
material of the average tannery and to obtain liquors of the necessary
strength.
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