After extraction the liquor is allowed to stand, and much insoluble
matter settles out--resins, wood, fibre, etc. The clarified and settled
liquor is then passed through a cooler up to about 55° C., and then run
into the decolorizing plant, a deep vat fitted with a copper steam coil
and mechanical stirrer attached to power. The best decolorizer is
bullock's blood, which is run into the vat and well mixed. The
temperature is next raised to about 70° C., causing the blood albumin to
coagulate. It carries down with it a little tannin, but much colouring
matter. After standing a few hours the settled liquor is run off direct
to the evaporator. A multiple-effect evaporator is usually employed, and
the concentrated liquor, which has a strength of about 25° Beaumé, is
run into suitable oak casks. The extracts contain 27-32 per cent.
tannin. An extract made with open vats has about 7 per cent. soluble
non-tanning matters, whilst a "pressure extract" may contain up to 12
per cent. of these "non-tans." Pressure extracts obtain also a better
yield of tannin, which more than compensates for the slightly lower
price. Open extraction yields, however, the purer product and an extract
with better penetrating powers, and is consequently the more suitable
for drum tannages. Chestnut extract is extensively used by the heavy
leather tanners.
=Oakwood Extract= is manufactured from the wood of the common oak
(_Quercus robur_). The centre of the industry has been the oak forest of
Slavonia. The wood contains 2-4 per cent. of a tannin very similar to
that of chestnut wood, but somewhat more astringent.
The manufacture is also similar to that of chestnut extract, but
decolorization is often omitted, and greater care has to be taken and in
other ways to keep the colour within limits. One of these is to strip
the wood more completely of bark. Another is to operate at as low a
temperature as possible, about 110° C. The extraction is made in large
circular vats about 14 feet high and holding about two tons material. A
battery is composed of about eight vats or extractors. Open extraction
is used, and the liquor is passed forward after 2-3 hours' boiling, so
that the material is spent in about 24 hours. A liquor of about 5° Bé
(36 Bkr.) is obtained, and the strength of the material reduced from 4
to 1/4 per cent. of tannin. Getting rid of insoluble matter is a
difficulty, and is attained by settling, by rapidly cooling, and then
passing through a filter press of wood. For evaporation a double-effect
vacuum pan is preferred, which operates first at about 113° F., and
afterwards at 140° F. with a higher vacuum. The liquor is concentrated
from 5° to 25° Beaumé (s.g. 1.036 and 1.210 respectively).
The extract has a much higher colour than chestnut, and is not used now
as much as some years ago. As the principal supply was German, it has
been unavailable.
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