Appletons' Popular Science Monthly, May 1899: Volume LV, No. 1, May 1899Various
History
Appletons' Popular Science Monthly, May 1899: Volume LV, No. 1, May 1899
Various
Science -- Periodicals; Technology -- Periodicals
Within comparatively recent years several gases have been liquefied on
the large scale by means of pressure. These are ammonia, carbonic
acid, nitrous oxide, and chlorine. Ammonia is used for producing low
temperatures, as in breweries and in cold-storage plants and in the
manufacture of ice; carbonic acid, for fire extinguishers and for
charging beer with the gas; nitrous oxide, for producing anæsthesia;
and chlorine in connection with several branches of chemical
manufacture. The production of low temperatures by means of liquid
ammonia and of liquid carbonic acid will be more fully dealt with
further on, when the principles involved will be briefly presented. It
is to be borne in mind that these substances are liquefied by means of
pressure alone, at temperatures that are easily reached, so that it
appears that by mechanical pressure it is possible to produce low
temperatures. In 1869 an important fact was discovered by Andrews. It
was that for every gas there is a temperature above which it is
impossible to liquefy it by pressure. Thus, if chlorine is at any
temperature above 146° C. (294° F.) it can not be liquefied. This
temperature is called the "critical temperature" of chlorine. The
pressure to which the gas must be subjected at the "critical
temperature" in order that the gas may be liquefied is called the
"critical pressure." In the case of chlorine this is 93.5 atmospheres.
Now, the critical temperature of the gases that were called permanent
gases are very low--lower than could be reached by the means at the
command of earlier experimenters. The critical temperature of oxygen,
for example, is -118.8° C. (-182° F.), while that of nitrogen is -146°
C. (-230° F.). The critical pressures are 50.8 and 35 atmospheres
respectively. As there is no difficulty in obtaining these pressures,
the problem of liquefying oxygen and nitrogen and air resolves itself
into finding a method of producing temperatures below the critical
temperatures of these gases.
It is well known that a temperature somewhat below the freezing point
of water can be produced artificially by mixing ice and salt. The
ordinary ice-cream freezer is a familiar application of this method of
producing cold. Other freezing mixtures that are sometimes used
consist of calcium chloride and snow, that gives the temperature -48°
C. (-54.4° F.), and solid carbonic acid and ether, that is capable of
lowering the temperature to -100° C. (-148° F.). But even with the
latter mixture it is not possible to reach the critical temperature of
oxygen or that of nitrogen. How, then, is it possible to reach these
extremely low temperatures?
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