Appletons' Popular Science Monthly, May 1899: Volume LV, No. 1, May 1899Various
History
Appletons' Popular Science Monthly, May 1899: Volume LV, No. 1, May 1899
Various
Science -- Periodicals; Technology -- Periodicals
In order to answer this question it will be necessary to take into
consideration certain temperature changes that are observed when
solids are melted and liquids are boiled, as well as when gases are
liquefied and liquids are frozen. When heat is applied to a mass of
ice at its melting point it melts and forms a mass of water having the
same temperature. Heat disappears in the operation. It is stored up in
the water. This disappearance of heat that accompanies the melting of
ice can be shown in a very striking way by mixing a certain weight of
ice with the same weight of water that has been heated to 80° C. (176°
F.). The ice will melt and all the water obtained will be found to
have the temperature of the melting ice--that is, 0° C. (32° F.). The
water of 80° C. is thus cooled down to 0° by the melting of the ice.
Again, when heat is applied to water its temperature rises until the
boiling point is reached. Then it is converted into vapor, but this
vapor has the temperature of the boiling water. During the process of
boiling there is no rise in the temperature of the water or of the
vapor. Heat disappears, therefore, or is used up in the process of
vaporization. Similar phenomena are observed whenever a solid is
melted or a liquid is boiled. When, however, a gas is liquefied it
gives up again the heat that is absorbed by it when it is formed from
a liquid; and so also when a liquid solidifies it gives up the heat it
absorbs when it is formed from a solid.
But it is not necessary that a gas should be converted into a liquid
in order that it should give up heat. Whenever it is compressed it
becomes warmer. Some of the heat stored up in it is, as it were,
squeezed out of it. Conversely, whenever a gas expands, it takes up
heat and, of course, surrounding objects from which the heat is taken
become colder. Now, it is a comparatively simple matter to compress
air. Every wheelman knows that, and he also knows that the process
causes a rise in temperature; at least he knows it if he uses a small
hand pump. With large pumps run by steam any desired pressure can be
reached. This is simply a question of securing the proper engines, and
vessels sufficiently strong to stand the pressure. It has already been
pointed out that several gases are now liquefied on the large scale by
means of pressure. It is to be noted that low temperatures can be
produced by converting certain gases, such as ammonia and carbonic
acid, into liquids, and by compressing certain gases, as, for example,
air. When liquefied gases are used it is only necessary to allow them
to pass rapidly into the gaseous state, when more or less heat is
absorbed. This is the basis for the use of liquid ammonia in the
manufacture of ice. A vessel containing the liquid ammonia is placed
in another containing water. The inner vessel being opened, the liquid
ammonia is rapidly converted into the gas; heat is absorbed from the
water; it freezes. When a vessel containing liquid carbonic acid is
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