Appletons' Popular Science Monthly, May 1899: Volume LV, No. 1, May 1899Various
History
Appletons' Popular Science Monthly, May 1899: Volume LV, No. 1, May 1899
Various
Science -- Periodicals; Technology -- Periodicals
opened so that the gas that is formed escapes through a small valve,
so much heat is absorbed that a part of the liquid carbonic acid is
itself frozen. In this case the substance is present in all three
states of aggregation--the solid, the liquid, and the gaseous. The use
of a mixture of ether and solid carbonic acid as a freezing mixture
has already been referred to. Its value depends, of course,
principally upon the fact that solid carbonic acid is liquefied, and
the liquid then converted into gas, both of which operations involve
absorption of heat.
We are now prepared to understand the important experiments of
Cailletet and of Pictet, the results of which were published in 1877.
It should be said that they worked independently of each
other--Cailletet in Paris and Pictet in Geneva. Pictet liquefied
carbonic acid and sulphur dioxide by pressure. The liquid carbonic
acid was passed through a tube that was surrounded by liquid sulphur
dioxide boiling in a partial vacuum. The liquid carbonic acid thus
cooled was then boiled under diminished pressure in a jacket
surrounding a tube in which the gas to be liquefied was contained
under high pressure. When this gas was allowed to escape from a small
opening its temperature was so reduced by the expansion that a part of
it was liquefied in the tube and passed off as a liquid. Cailletet
worked in essentially the same way, but on a smaller scale. Neither of
these experimenters liquefied oxygen or nitrogen on the large scale,
but they pointed out the way that must be followed in order that
success may be attained. They destroyed the belief in "permanent"
gases.
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