Buffon's Natural History. Volume 10 (of 10): Containing a Theory of the Earth, a General History of Man, of the Brute Creation, and of Vegetables, Minerals, &c. &cBuffon, Georges Louis Leclerc, comte de
History
Buffon's Natural History. Volume 10 (of 10): Containing a Theory of the Earth, a General History of Man, of the Brute Creation, and of Vegetables, Minerals, &c. &c
Buffon, Georges Louis Leclerc, comte de
Natural history
This seems to indicate that the most essential difference between
combustible matters and those which are not so, consists in the latter
containing only a few or none of the light, ethereal, and oily matters
susceptible of an expansive motion, or, at least, if they contain them,
that they are fixed, so that they cannot exercise their volatility
whenever the force of the fire is not strong enough to surmount the
force of adhesion which retains them united to the fixed parts of
matter. It may be said that this induction is confirmed by a number of
observations well known to chemists; but what appears to be less so,
and which, nevertheless, is a necessary consequence of it, is, that
all matter may become volatile when the expansive force of the fire
can be rendered superior to the attractive force which holds the parts
of matter united; for though to produce a fire sufficiently strong it
may require better constructed mirrors than any at present known, yet
we are certain that fixity is only a relative quality, and that there
is no matter absolutely so, since heat dilates the most fixed bodies.
Now is not this dilation the index of a beginning separation, that may
be augmented with a degree of heat to fusion, and with a still greater
heat to volatilisation?
Combustion supposes something more than volatilisation; it is not
sufficient that the parts of matter be sufficiently separated to be
carried off by those of heat; they must also be of an analogous nature
to fire; without that, mercury, being the most fluid next to air, would
also be the most combustible, whereas experience demonstrates, that
though very volatile it is not combustible. Matter is, in general,
composed of four principal substances, called _elements_, that is,
earth, water, air, and fire. Those in which earth and water predominate
will be fixed, and will only become volatile by the action of heat;
and those which contain most air and fire will be the only real
combustibles. The great difficulty here is clearly to conceive how air
and fire, both so volatile, can fix and become constituent parts of all
bodies.
Fire, by absorbing air, destroys the spring. Now there are but two
methods of destroying a spring, either by compressing it till it
breaks, or extending it till it loses its effect. It is plain that
fire cannot destroy air by compression, since the least degree of heat
rarefies it; on the contrary, by a very strong heat the rarefaction of
the air will be so great that it will occupy a space thirteen times
more extended than that of its general volume; and by this means the
spring becomes weakened, and it is in this state that it can become
fixed, and unite with other bodies.
Public-domain text, read in full here on John Shaqi.
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