Classics of modern science : $b (Copernicus to Pasteur)
History
Classics of modern science : $b (Copernicus to Pasteur)
Science; Science -- History
On reviewing the various compound gases most generally known, I only
find examples of duplication of the volume relatively to the volume of
that one of the constituents which combines with one or more volumes
of the other. We have already seen this for water. In the same way,
we know that the volume of ammonia gas is twice that of the nitrogen
which enters into it. M. Gay-Lussac has also shown that the volume of
nitrous oxide is equal to that of the nitrogen which forms part of
it, and consequently is twice that of the oxygen. Finally, nitrous
gas, which contains equal volumes of nitrogen and oxygen, has a
volume equal to the sum of the two constituent gases, that is to say,
double that of each of them. Thus in all these cases there must be a
division of the molecule into two; but it is possible that in other
cases the division might be into four, eight, &c. The possibility of
this division of compound molecules might have been conjectured _a
priori_; for otherwise the integral molecules of bodies composed
of several substances with a relatively large number of molecules,
would come to have a mass excessive in comparison with the molecules
of simple substances. We might therefore imagine that nature had some
means of bringing them back to the order of the latter, and the facts
have pointed out to us the existence of such means. Besides, there
is another consideration which would seem to make us admit in some
cases the division in question; for how could one otherwise conceive
a real combination between two gaseous substances uniting in equal
volumes without condensation, such as takes place in the formation of
nitrous gas? Supposing the molecules to remain at such a distance that
the mutual attraction of those of each gas could not be exercised,
we cannot imagine that a new attraction could take place between the
molecules of one gas and those of the other. But on the hypothesis
of division of the molecule, it is easy to see that the combination
really reduces two different molecules to one, and that there would be
contraction by the whole volume of one of the gases if each compound
molecule did not split up into two molecules of the same nature. M.
Gay-Lussac clearly saw that, according to the facts, the diminution of
volume on the combination of gases cannot represent the approximation
of their elementary molecules. The division of molecules on combination
explains to us how these two things may be made independent of each
other.
III.
Public-domain text, read in full here on John Shaqi.
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