Classics of modern science : $b (Copernicus to Pasteur)
History
Classics of modern science : $b (Copernicus to Pasteur)
Science; Science -- History
of imbibition, as fat, sugar, tartaric acid, &c. The bodies capable of
imbibition, therefore, either do not crystallize at all, or they do so
under a form so different from the crystal that they are not recognized
as such.
Let us inquire what would most probably ensue if material capable of
imbibition crystallized according to the ordinary laws, what varieties
from the common crystals would be most likely to show themselves,
assuming only that the solution has permeated through the parts of
the crystal already formed, and that new molecules can therefore
be deposited between them. The ordinary crystals increase only by
apposition; but there may be an important difference in the mode of
this apposition. If the molecules were all deposited symmetrically
one upon another, we might indeed have a body of a certain external
form like a crystal; but it would not have the structure of one,
it would not consist of layers. The existence of this laminated
structure in crystals presupposes a double kind of apposition of their
molecules; for in each layer the newly-deposited molecules coalesce,
and become continuous with those of the same layer already present;
but those molecules which form the adjacent surfaces of two layers
do not coalesce. This is a remarkable peculiarity in the formation
of crystals, and we are quite ignorant of its cause. We cannot yet
perceive why the new molecules, which are being deposited on the
surface of a crystal (already formed up to a certain point), do not
coalesce and become continuous with those already deposited, like the
molecules in each separate layer, instead of forming, as they do, a
new layer; and why this new layer does not constantly increase in
thickness, instead of producing a second layer around the crystal, and
so on. In the meantime we can do no more than express the fact in the
form of a law, that the coalescing molecules are deposited rather along
the surface beside each other, than in the thickness upon one another,
and thus, as the breadth of the layer depends upon the size of the
crystal, so also the layer can attain only a certain thickness, and
beyond this, the molecules which are being deposited cannot coalesce
with it, but must form a new layer.
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