Classics of modern science : $b (Copernicus to Pasteur)
History
Classics of modern science : $b (Copernicus to Pasteur)
Science; Science -- History
If we now assume that bodies capable of imbibition could also
crystallize, the two modes of junction of the molecules should be
shown also by them. Their structure should also be laminated, at least
there is no perceptible reason for a difference in this particular,
as the very fact of layers being formed in common crystals shows that
the molecules need not be all joined together in the most exact manner
possible. The closest possible conjunction of the molecules takes place
only in the separate layers. In the common crystals this occurs by
apposition of the new molecules on the surface of those present and
coalescence with them. In bodies capable of imbibition, a much closer
union is possible, because in them the new molecules may be deposited
by intussusception between those already present. It is scarcely,
therefore, too bold an hypothesis to assume, that when bodies capable
of imbibition crystallize, their separate layers would increase by
intussusception; and that this does not happen in ordinary crystals,
simply because it is impossible.
Let us then imagine a portion of the crystal to be formed: new
molecules continue to be deposited, but do not coalesce with the
portion of the crystal already formed; they unite with one another
only, and form a new layer, which, according to analogy with the common
crystals, may invest either the whole or a part of the crystal. We
will assume that it invests the entire crystal. Now, although this
layer be formed by the deposition of new molecules between those
already present instead of by apposition, yet this does not involve
any change in the law, in obedience to which the deposition of the
coalescing molecules goes on more vigorously in two directions,
that is, along the surface, than it does in the third direction
corresponding to the thickness of the layer; that is to say, the
molecules which are deposited by intussusception between those already
present, must be deposited much more vigorously between those lying
together along the surface of the layer than between those which lie
over one another in its thickness. This deposition of molecules side
by side is limited in common crystals by the size of the crystal, or
by that of the surface on which the layer is formed; the coalescence
of molecules therefore ceases as regards that layer, and a new one
begins. But if the layers grow by intussusception in crystals capable
of imbibition, there is nothing to prevent the deposition of more
molecules between those which lie side by side upon the surface, even
after the lamina has invested the whole crystal; it may continue to
grow without the law by which the new molecules coalesce requiring to
be altered. But the consequence is, that the layer becomes, in the
first instance more condensed, that is, more solid substance is taken
into the same space; and afterwards it will expand and separate from
the completed part of the crystal so as to leave a hollow space between
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account