[Footnote 96: H. F. Osborn: Men of the Old Stone Age, N. Y., 1915; J. M. Tyler: The New Stone Age in Northwestern Europe, N. Y., 1920.] CHAPTER XIII THE CHANGING COMPOSITION OF OCEANS AND ATMOSPHERE Having discussed the climatic effect of movements of the earth's crust during the course of geological time, we are now ready to consider the corresponding effects due to changes in the movable envelopes--the oceans and the atmosphere. Variations in the composition of sea water and of air and in the amount of air must almost certainly have occurred, and must have produced at least slight climatic consequences. It should be pointed out at once that such variations appear to be far less important climatically than do movements of the earth's crust and changes in the activity of the sun. Moreover, in most cases, they are not reversible as are the crustal and solar phenomena. Hence, while most of them appear to have been unimportant so far as climatic oscillations and fluctuations are concerned, they seemingly have aided in producing the slight secular progression to which we have so often referred. There is general agreement among geologists that the ocean has become increasingly saline throughout the ages. Indeed, calculations of the rate of accumulation of salt have been a favorite method of arriving at estimates of the age of the ocean, and hence of the earliest marine sediments. So far as known, however, no geologist or climatologist has discussed the probable climatic effects of increased salinity. Yet it seems clear that an increase in salinity must have a slight effect upon climate. Salinity affects climate in four ways: (1) It appreciably influences the rate of evaporation; (2) it alters the freezing point; (3) it produces certain indirect effects through changes in the absorption of carbon dioxide; and (4) it has an effect on oceanic circulation. (1) According to the experiments of Mazelle and Okada, as reported by Kruemmel,[97] evaporation from ordinary sea water is from 9 to 30 per cent less rapid than from fresh water under similar conditions. The variation from 9 to 30 per cent found in the experiments depends, perhaps, upon the wind velocity. When salt water is stagnant, rapid evaporation tends to result in the development of a film of salt on the top of the water, especially where it is sheltered from the wind. Such a film necessarily reduces evaporation. Hence the relatively low salinity of the oceans in the past probably had a tendency to increase the amount of water vapor in the air. Even a little water vapor augments slightly the blanketing effect of the air and to that extent diminishes the diurnal and seasonal range of temperature and the contrast from zone to zone.