In the above table the increase of carbon and the decrease of oxygen is
well brought out; the hydrogen also on the whole decreases, although with
some irregularity. The exact course of the chemical change which occurs
during the passage of wood into coal is at present involved in obscurity.
The oxygen may be eliminated in the form of water or of carbon dioxide or
both; some of the carbon is got rid of in the form of marsh gas, a
compound of carbon and hydrogen, which forms the chief constituent of the
dangerous "fire-damp" of coal mines.
Marsh gas is an inflammable gas which becomes explosive when mixed with
air and ignited; it often escapes with great violence during the working
of coal seams, the jets blowing out from the coal or underclay with a
rushing noise, indicative of the high pressure under which the hydrocarbon
gas has accumulated. These jets of escaping gas are known amongst miners
as "blowers." If the air of a mine contains a sufficient quantity of the
gas, and a flame accidentally fires the mixture, there results one of
those disastrous explosions with which the history of coal mining has
unfortunately only made us too familiar.
From the account of coal which has thus far been rendered, it will be seen
that as a source of mechanical power, we are far from using it as
economically as could be desired; and when we look at our open grates with
clouds of unburnt carbon particles escaping up the chimney, and so
constructed that only a small fraction of the total heat warms our rooms,
it will be seen that the tale of waste is still more deplorable. But we
are at present rather concerned with what we actually do get from coal
than with what we ought to get from it, and here, when we come to deal
with the various material products, we shall have a better account to
present.
If instead of heating coal in contact with air and allowing it to burn, we
heat it in a closed vessel, such as a retort, it undergoes decomposition
with the formation of various gaseous, liquid, and solid products. This
process of heating an organic compound in a closed vessel without access
of air and collecting the products, is called destructive distillation.
The tobacco-pipe experiment of our boyhood is our first practical
introduction to the destructive distillation of coal. We put some powdered
coal into the bowl of the pipe, plaster up the opening with clay and then
insert the bowl in a fire, allowing the stem to project from between the
bars of the grate. In a few minutes a stream of gas issues from the
orifice of the stem; on applying a light it burns with a luminous flame,
and we have made coal-gas on a small scale.
Public-domain text, read in full here on John Shaqi.
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