In the destructive distillation of organic substances, such as wood or
coal, there are always produced four things--gas, watery liquid, and
viscous products known as tar, while a residue of coke or charcoal is left
in the retort. This is a very old observation, and was made so long ago
that it becomes interesting as a point in the history of applied science
to know who first submitted coal to destructive distillation. According to
Dr. Gustav Schultz, we must credit a German with this observation, which
was made towards the end of the seventeenth century (about 1680) by a
chemist named Johann Joachim Becher. The experiment is described in such a
quaint manner that the exact words of the author are worthy of being
reproduced, and the passage is here given as translated by Dr. Lunge in
his work on _Coal Tar and Ammonia_--
"In Holland they have peat, and in England pit-coals; neither of them is
very good for burning, be it in rooms or for smelting. But I have found a
way, not merely to burn both kinds into good coal (coke) which not any
more smokes nor stinks, but with their flame to smelt equally well as with
wood, so that a foot of such coal makes flames 10 feet long. That I have
demonstrated with pit-coal at the Hague, and here in England at Mr.
Boyles', also at Windsor on the large scale. In this connection it is also
noteworthy that, equally as the Swedes make their tar from firwood, I have
here in England made from pit-coal a sort of tar which is equal to the
Swedish in every way, and for some operations is even superior to it. I
have made proof of it on wood and on ropes, and the proof has been found
right, so that even the king has seen a specimen of it, which is a great
thing in England, and the coal from which the tar has been taken out is
better for use than before."
This enterprising chemist, moreover, brought his results to a practical
issue, for he secured a patent, in conjunction with Henry Serle, in 1681,
for "a new way of making pitch and tarre out of pit-coale, never before
found out or used by any other."
No less interesting is the work of our own clergy during the last century,
when many eminent divines appear to have devoted their leisure to
experimental science. Thus, about the year 1688 the Rev. John Clayton,
D.D., Dean of Kildare, went to examine a ditch two miles from Wigan in
Lancashire, the water in which had been stated to "burn like brandy" when
a flame was applied to it. The Dean ultimately traced the phenomenon to an
escape of inflammable gas from an underlying coal seam, and he followed up
the matter experimentally by studying the destructive distillation of
Wigan coal in retorts. The results were communicated to the Hon. Robert
Boyle, but were not published till after the death of the latter, and long
after the death of the author. The following account is taken from the
abridged edition of the _Philosophical Transactions_ (1739):--
Public-domain text, read in full here on John Shaqi.
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