[Illustration: FIG. 6.--Sectional diagram of tar-still with arched bottom.
The fireplace is at _i_; the hot gases pass over the bridge _k_ and
through _g_ into the flues _h_, _h_. The pipe at _c_ is to supply the
still with tar; _a_ is the exit pipe connected with the condenser, and _b_
a man-hole for cleaning out the still. The condenser and bottom pipe for
drawing off pitch have been omitted to avoid complication.]
It is customary at the present time to collect four distinct fractions
from the period when the tar begins to boil quietly, _i.e._ from the
point when the small quantity of watery liquor which is unavoidably
entangled with the tar has distilled over, by which time the temperature
in the still is about 110 deg. C. The small fraction that comes over up to
this temperature constitutes what the tar-distiller calls "first
runnings." From 110 deg. C. to 210 deg. C. there comes over a limpid inflammable
liquid known as "light oil," and this is succeeded by a fraction which
shows a tendency to solidify on cooling, owing to the separation of a
solid crystalline hydrocarbon known as naphthalene. This last fraction,
boiling between 210 deg. C. and 240 deg. C., is known as "carbolic oil," because
it contains, in addition to the naphthalene, the chief portion of the
carbolic acid present in the tar. From 240 deg. C. to 270 deg. C. there comes over
another fraction which shows but little tendency to solidify in the
condensing coil, and which is known as "heavy oil," or "creosote oil."
From 270 deg. C. up to the end of the distillation there distils a fraction
which is viscid in consistency, and has a tendency to solidify on cooling
owing to the separation of another crystalline hydrocarbon known as
anthracene, and which gives the name of "anthracene oil" to this last
fraction. When the latter has been collected there remains in the still
the black viscid substance known as pitch, which is obtained of any
desired consistency by leaving more or less of the anthracene oil mixed
with it, or by afterwards mixing it with the heavy oil from previous
distillations. The process carried out in the tar-still thus separates the
tar into--(1) First runnings, up to 110 deg. C. (2) Light oil, from 110 deg. to
210 deg. C. (3) Carbolic oil, from 210 deg. to 240 deg. C. (4) Creosote oil, from 240 deg.
to 270 deg. C. (5) Anthracene oil, from 270 deg. to pitch. (6) Pitch, left in
still.
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