In four years the accidental observation of Natanson and Hofmann, made, be
it remembered, in the course of abstract scientific investigation, had
thus developed into an important branch of manufacture. A demand for
aniline on an increased scale sprung up, and the light oils of coal-tar
became of still greater importance. The operations of the tar-distiller
had to undergo a corresponding increase in magnitude and refinement; the
production of nitrobenzene and necessarily of nitric acid had to be
increased, and a new branch of manufacture, that of arsenic acid from
arsenious acid and nitric acid, was called into existence. Perkin's mauve
prepared the way for the manufacture of aniline, and the discovery of a
good process for the production of magenta increased this branch of
manufacture to a remarkable extent. Still later in the history of the
magenta manufacture, attempts were made, with more or less success, to use
nitrobenzene itself as an oxidizing agent, and a process was perfected in
1869 by Coupier, which is now in use in many factories.
The introduction of magenta into commerce marks an epoch in the history of
the coal-tar colour industry--pure chemistry and chemical technology both
profited by the discovery. The brilliant red of this colouring-matter is
objected to by modern aestheticism, but the dye is still made in large
quantities, its value having been greatly increased by a discovery made
about the same time by John Holliday and the Baden Aniline and Soda
Company, and patented by the latter in 1877. Magenta is the salt of a base
now known as rosaniline, and it belongs therefore to the class of basic
colouring-matters. The dyes of this kind are as a group less fast, and
have a more limited application than those colouring-matters which possess
an acid character, so that the discovery above referred to--that magenta
could be converted into an acid without destroying its colouring power by
acting upon it with very strong sulphuric acid--opened up a new field for
the employment of the dye, and greatly extended its usefulness. In this
form the colouring-matter is met with under the name of "acid magenta."
Public-domain text, read in full here on John Shaqi.
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