It must be understood that the production of magenta from aniline by the
oxidizing action of arsenic acid or nitrobenzene is the result of chemical
change; the colouring-matter is no more present in the aniline than the
latter is contained in the benzene. And just in the same way that the
colourless aniline oil by chemical transformation gives rise to the
intensely colorific magenta, so the latter by further chemical change can
be made to give rise to whole series of different colouring-matters, each
consisting of definite chemical compounds as distinct in individuality as
magenta itself. Thus in 1860, about the time when the arsenic acid process
was inaugurated, two French chemists, Messrs. Girard and De Laire,
observed that by heating rosaniline for some time with aniline and an
aniline salt, blue and violet colouring-matters were produced. This
observation formed the starting-point of a new manufacture proceeding from
magenta as a raw material. The production of the new colouring-matters was
perfected by various investigators, and a magnificent blue was the final
result. But here also the dye was of a basic character, and being
insoluble in water had only a limited application, as a spirit bath had to
be used for dissolving the substance. In 1862, however, an English
technologist, the late E. C. Nicholson, found that by the action of strong
sulphuric acid the aniline blue could be rendered soluble in water or
alkali, and the value of the colouring-matter was enormously increased by
this discovery. The basic and slightly soluble spirit blue was by this
means converted into acid blues, which are now made in large quantities,
and sold under the names of Nicholson's blue, alkali blue, soluble blue,
and other trade designations. There is at the present time hardly any
other blue which for fastness, facility of dyeing, and beauty can compete
with this colouring-matter introduced by Nicholson as the outcome of the
work of Girard and De Laire.
Other transformations of rosaniline have yet to be chronicled. In 1862
Hofmann found that by acting upon this base--the base of magenta--with the
iodide of methyl, violet colouring-matters were produced, and these were
for some years extensively employed under the name of Hofmann's violets.
And still more remarkable, by the prolonged action of an excess of methyl
iodide upon rosaniline, Keisser found that a green colouring-matter was
formed. The latter was patented in 1866, and the dye was for some time in
use under the name of "iodine green." The statement that technology
profited by the introduction of magenta has therefore been justified.
Public-domain text, read in full here on John Shaqi.
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