The mixing, in equal or other proportions, of the potassium
and ammonium salts has been recommended, but there is no real gain
or sufficient reason for preferring any of these combinations to the
ammonium salt alone. Besides the chromates of the alkalis, several
other salts as well as acids are used in Collotype printing, although
seldom, and then only in small quantities and for special purposes,
such, for instance, as hardening the print layer, or for the purpose
of facilitating the retention of moisture in the film. For the former
purpose small quantities of chrome alum are sometimes added; while for
the latter chloride of sodium or chloride of calcium are sometimes
added to the chromated gelatine solution at the time of coating the
plates, or are added as ingredients to the so-called etching or damping
solution which is frequently applied to the plates during the printing.
Glycerine answers for this purpose, and is to be preferred. It should
be borne in mind that all additions to the film to facilitate its
retention of moisture lessen its adhesiveness to its support. And with
regard to the direct addition of the substances mentioned to the film
during the preparation of the plates, it is not very apparent how such
readily-soluble matters can remain in the film after the prolonged and
careful washing the plates should be subjected to after exposure in the
printing frame. On these grounds the addition of such substances to
the damping solution is more rational and certainly more effective.
=Alum= and =Chrome-Alum= causes the gelatine to set sooner without
precipitation, and harden the layer considerably after drying, and
although gelatine, as well as glue, always contains more or less
chondrin, which is precipitated by alum, great care is necessary in
the addition of the latter; and it is better that such addition should
be made immediately before the hot solution be poured upon the plates,
otherwise a precipitation will ensue, which, although very finely
divided and at first scarcely visible, will become more apparent
during the drying of the plates, and finally show in the picture in
innumerable white spots.
=Silicate of Soda= is almost indispensable as a substratum in the
preparation of collotype plates, although many practical workers still
adhere to the method originally proposed and practised by J. Albert, of
Munich, who used as a substratum a chromated solution of gelatine and
albumen, rendered either partially or wholly insoluble by exposure to
light. The silicate is here considered as having about the consistency
of syrup. If more fluid the adhesive power of the substratum will not
realise expectations, and the plates will require very careful handling
if even a few hundred impressions are required.
Public-domain text, read in full here on John Shaqi.
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