The composition of the film, the exposure of the plate through the
back, and the careful treatment of the layer in the actual printing
operations are all matters which considerably affect the “life” of the
plate, and to which we shall again return.
=Chloride of Zinc= is used for hardening special parts of the collotype
plate, and is easily prepared by dissolving—to saturation—sheet zinc in
hydrochloric acid, filtering, and reducing as circumstances may demand.
=Tannin= and =Tannic Acid= in strong solution harden the film, and
may be applied to certain parts to cause it to “take” the ink. For
instance, to remove, or rather harden, spots which refuse the ink and
consequently show upon a dark ground; and also to write names or titles
to the plates. Written additions of this character must, of course, be
reversed, as in lithography. The addition of tannin to the chromated
gelatine before coating the plate is recommended by Waterhouse, he
considering such addition confers greater lasting power to the films so
treated.
=Cyanide of Potassium and Ammonia.=—All alkalis or carbonates of the
alkalis have a directly opposite effect upon the printed layer to
that last referred to. By the judicious use of one or the other of
these agents spots printing light or dark may be either removed or
considerably modified.
=Glycerine and Sugar= and similar easily soluble organic substances,
added to the chromated gelatine, would assist the easier and evener
damping of the plate, but render it more susceptible to damage, and
the desired effect is better attained by suitable additions to the
damping water.
=Organic Acids.=—Citric acid and tartaric acid are recommended as
additions to the chromated gelatine, partially as influencing the
so-called “grain,” and also as additions to the damping solution to
facilitate the production of cleaner prints. Experience with these
substances shows that the print layer suffers from their use, and for
clearing up a plate inclined to yield dirty impressions a weak solution
of ammonia is far preferable.
=Nitric Acid= has even been recommended for occasionally damping the
plate in certain cases, after which the most delicate half-tones should
be reproducible. An experienced collotypist ought never to be under the
necessity of adopting such desperate remedies, which more often than
not rapidly and entirely spoil the plate, and it is better to at once
prepare a new one.
=Ox Gall= remains to be mentioned as exercising a beneficial influence
upon the print layer under certain circumstances. It considerably
hardens the gelatine, and tends to reduce the annoying tendency of
the film to adhere to the paper in the high lights. Ox gall was first
used at the Royal Printing Works in the “glass” printing process there
utilised for the reproduction of line subjects. Some operators of
eminence consider that in collotype its use should be strictly confined
to lineal representations, as by its continued use the half-tones are
partially lost.
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