Colour Measurement and MixtureAbney, William de Wiveleslie, Sir
Science
Colour Measurement and Mixture
Abney, William de Wiveleslie, Sir
Color
The fact that red, yellow, and blue cannot be primary colours has been
mentioned, as even now it is sometimes taught that they are so. As long
as the theory of colour principally lay with artists there was
reasonable ground for their assumption, since they worked with impure
colours, viz. those of pigments; and as we shall see later on the truth
of the assumption agreed with such experiments as they would make. When,
however, the question was taken up by the physicist with more exact
methods of experimenting, and with pure colours, the falsity of the old
triad was soon capable of proof.
To return from our digression: how it is that three mixed colours can
give the sensation of white light is at first sight hard to understand;
but a reference to the action of light on a photographic salt helps us
in some degree. In the case of a sensitive salt, such as the
bromo-iodide of silver, we find that a chemical decomposition is caused
by the violet end of the spectrum, and is only feebly affected by any
other part, though with prolonged exposure even the red will cause it.
The annexed figure (Fig. 33) gives the idea of the relative action of
different parts of this violet portion.
Fig. 33.--Curve of Sensitiveness of Silver Bromo-iodide.
The height of the curve shows the relative effects produced. Now this
curve is not symmetrical, but has a maximum effect nearer to the violet
end of the spectrum than to the red. The atomic composition of the
silver bromo-iodide is probably two atoms of silver and one of bromine
and one of iodine oscillating together, and we can conceive of some one
atom, the period of whose swings in its molecule is isochronous with
some wave-length of light. Further, we can conceive that, like a
pendulum whose vibrations are increased in magnitude by well-timed
blows, the swing of the atom is also increased, and that eventually it
gets beyond the sphere of the attraction of its parent molecule, leaves
it, and is attracted to some neighbouring molecule of different
constitution, and that thus a chemical change is induced. This we can
conceive, but how can other waves, which are not isochronous with the
rhythmic swing of the atoms, alter the composition of the molecule? If
we have an impulse given to a pendulum exactly timed with the period of
oscillation, there is no doubt that the swing is increased. If we have
one nearly in accord, it will be found that though the swings are not
increased in amplitude so greatly as when there is perfect accord, yet
an increased swing is given, and as exact accord is removed further and
further, so the increase in the swing of the pendulum gets smaller and
smaller. In somewhat the same manner it is possible that many series of
waves, differing in wave-length, and therefore in periods of
oscillation, may be capable of increasing the amplitude of a swing, and
with the photographic salt this probably occurs, with the result which
we see in the above figure. Suppose in the eye we have three such
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