Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume ICooley, Arnold James
Science
Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume I
Cooley, Arnold James
Formulas, recipes, etc.; Industrial arts -- Dictionaries; Technology -- Dictionaries
case the distillatory vessel is imbedded in sand supported by fire-brick,
and is not exposed directly to the heat of the furnace. Before commencing
the distillation the joints are all well luted, to avoid leakage. An
excellent plan is to pass the gas, as it leaves the retort, through a
silver or pewter ‘worm’ or ‘refrigerator’ set in a tub supplied with a
stream of very cold water; by which it will be sufficiently cooled before
it reaches the ‘receivers’ to obviate the necessity of any further
attention to them than keeping the cloths wrapped round them constantly
moistened with cold water. The lower end of the ‘worm’ should be
connected, by means of a balloon-shaped ‘adopter,’ with the ‘still,’ and
the upper end with the first ‘receiver,’ the use of the balloon being to
intercept any volatilised ammonia-salt that might be accidentally driven
over by the heat being too high, or too suddenly raised.
The heat should be gradually applied, and very gradually raised, to
prevent any of the sal ammoniac or sulphate being volatilised
undecomposed; and even towards the end of the process it should not even
approach redness.
The lime is best ‘slaked’ and ‘papped’ with about 4 parts of water; as a
lower heat is then required to expel the gas, and it passes over more
easily and fully than when less water is employed. This is absolutely
necessary when the sulphate is the ammonia-salt used; as otherwise the
residuum of ‘sulphate of lime’ would become so hard that it could not be
easily removed from the retort.
The gas being wholly expelled from the retort, or other distillatory
vessel, it is disconnected from the receivers, and (when sal ammoniac has
been employed) the heat is raised sufficiently high to fuse the residual
chloride of calcium, which is then at once baled or poured out. Glass
retorts often suffer fracture at this point; but if they escape now, it
generally happens that they are broken when heat is applied for a second
operation. Hence, according to Prof. Muspratt, it is rare to find a
retort, even when carefully handled, that will stand two operations.
When crude sulphate of ammonia is employed it is advisable to have only a
little water in the first receiver, which is placed there merely to purify
the gas which passes through it, and to retain any traces of volatile
empyreumatic or oily matter which may be carried over with it.
Pure solution of ammonia is most easily obtained from ‘sal ammoniac,’ but
crystallised sulphate of ammonia, often crude, is more commonly employed,
on account of its lower price.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account