Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume ICooley, Arnold James
Science
Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume I
Cooley, Arnold James
Formulas, recipes, etc.; Industrial arts -- Dictionaries; Technology -- Dictionaries
Another method adopted, particularly on the Continent, and one equally
applicable to any crude ammoniacal liquor rich in free ammonia or its
carbonates, is to employ sulphate of lime instead of sulphuric acid to
neutralise the alkali. For this purpose the ammoniacal liquor is passed
through a series of three or four covered wooden filters lined with lead,
each containing a layer of crushed gypsum to the depth of 3 or 4 inches.
These filters are usually set on ‘stages’ one above another, and each
communicates with a cistern placed beneath it by means of a leaden pipe
furnished with a stop-cock. This last is not opened untill the liquor has
remained some little time in the filter; and a pump throws back once, or
oftener, upon each filter, what has already passed through it, before it
is allowed to run into the next lower one. The ‘liquor’ in each filter is
not allowed to stand higher than from 2 to 3 inches above the surface of
the gypsum; and the lowest or last filter is supplied with fresh gypsum at
each separate charge of fresh liquor. A little water is lastly passed
through the filters to wash out the portion of ammoniacal liquor absorbed
or retained by the filtering media. In this way the gypsum of the filters
is converted into carbonate of lime at the expense of the carbonate of
ammonia in the solution; whilst the ammonia of the latter decomposes the
gypsum, and becomes converted into sulphate of ammonia, which, with some
free ammonia, is found in the filtrate. Sulphuric acid is next added to
the filtered liquor to completely neutralise the free and carbonated
alkali still existing in it; after which it is evaporated in a leaden
boiler, with frequent skimming to remove floating oil, until of the sp.
gr. 1·160. Chloride of sodium (common salt), in sufficient quantity to
convert all the sulphate of ammonia in the liquid into hydrochlorate, by
double decomposition, is now added, with constant stirring; after which
the clear portion is either pumped or syphoned off into a somewhat deep
reservoir or tank, where it is allowed to settle. The liquid after
sufficient repose is pumped from the reservoir to the boilers, and
evaporated, with frequent agitation, so long as the sulphate of soda now
existing in it falls to the bottom in granular crystals. These crystals
are, at intervals, scraped to the cooler portion of the pan or boiler,
whence they are removed by copper rakes and shovels, into
draining-hoppers, placed near the edges of the pan. The liquor in the
boiler is now a strong solution of sal ammoniac, but still containing a
little sulphate of soda, from which it has to be freed by crystallisation.
With this object it is further concentrated, and then run or pumped into
the crystallisers. In 30 or 40 hours, or longer, the mother-liquor is run
or pumped off. The mass of newly-formed crystals is then drained, and
slightly washed, first with a little weak solution of sal ammoniac, and
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