Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume ICooley, Arnold James
Science
Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume I
Cooley, Arnold James
Formulas, recipes, etc.; Industrial arts -- Dictionaries; Technology -- Dictionaries
next with a very little cold water; after which they are again well
drained. The crude HYDROCHLORATE OF AMMONIA, thus obtained, is converted
into the pure salts, by desiccation and sublimation, as before.
In France, where this method is very generally employed, the sublimation
is commonly conducted in stoneware or earthenware balloons or bottles
coated with loam, of about 18 to 20 inches in height in the body, and
either surmounted with inverted ‘cups’ or ‘heads’ 10 or 12 inches high, or
simply covered with a tile, when (in the latter case) the sublimate
collects in the upper part or neck of the balloon, which is above the
action of the fire. A number of these vessels are set on the dome of a
furnace, which is perforated with holes or slits, to allow the heat to
pass through; whilst their necks or heads are sheltered from the action of
the fire by plates of iron or earthenware, having semi-circular
indentations on their edges, so that when placed together they form a
level surface, through which the necks of the sublimers protrude, and fit
closely. The fire is nicely regulated, so as to cause the salts to
condense in the upper and cooler part of the vessels, or in the heads, as
the case may be; and great care is taken to occasionally clear the necks
with a skewer, to prevent choking, and consequent bursting.
In Scotland, where a similar process is also commonly pursued, the
sublimers, according to Dr Ure, are generally “cast-iron pots, lined with
fire-proof tiles; the condensation being effected in globular heads of
green glass, with which each of the iron pots are capped.”[51]
[Footnote 51: Ure’s ‘Dict. of Arts, M., & M.,’ 5th Edn., i, p. 143.]
_Ratio._ Gas-liquor contains carbonate of ammonium (chiefly), with
chloride, sulphate, hydrosulphate, cyanide, sulphocyanide, &c., of the
same radical. On neutralisation with hydrochloric acid, or sulphuric acid,
these are converted into chloride or sulphate of ammonium, according to
the acid used. By sublimation with chloride of sodium, the sulphate of
ammonium is converted, by double decomposition, into chloride of ammonium,
which sublimes; and sulphate of sodium, which remains in the subliming
pot. A similar change occurs when the solution of the sulphate, prior to
crystallisation, is decomposed by the addition of chloride of sodium, or
any other chloride. When the ‘gas-liquor’ is at once converted into
chloride of ammonium by the addition of hydrochloric acid, the sublimation
merely purifies the salt. Like changes occur when bone-spirit is employed.
_Comp._ Chemically considered, this salt consists of equal VOLUMES of
gaseous ammonia and hydrochloric acid gas condensed into the solid form;
or, by WEIGHT, according to the ammonia-theory, of——
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