Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume ICooley, Arnold James
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Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume I
Cooley, Arnold James
Formulas, recipes, etc.; Industrial arts -- Dictionaries; Technology -- Dictionaries
V. _From Alcohol._ (ALCOHOL VINEGAR, GERMAN ACETIC ACID.) In a bell-glass,
or an oblong glass case, perforated shelves are arranged, a few inches
apart, one above another, on which are placed a number of small flat
dishes of porcelain, earthenware, or wood. These dishes are filled with
spirit of wine or dilute alcohol; and over each is suspended a watch-glass
or capsule containing a portion of platinum-black; the whole being
arranged so that the platinum-black and the surface of the alcohol are not
more than 1-1/2 to 2 inches apart. Strips of porous paper are next so hung
in the case, that their bottom edges are immersed in the spirit, to
promote evaporation; and lastly, the apparatus, loosely covered, is set in
a light place at a temperature of from 70° to 90° Fahr.——the sunshine,
when convenient. In a short time the temperature of the platinum rises,
and the formation of acetic acid begins; and the condensed vapour trickles
down the sides of the glass and collects at the bottom of the case, whence
it is removed once or twice a day. (See _engr._) The product of a case of
twelve cubic feet content, with 7 or 8 oz. of platinum-powder, is capable
of producing daily, if well managed, nearly 1·31 lb. of hydrated acetic
acid from 1 lb. of absolute alcohol; 25 lbs. of platinum-powder and 300
lbs. of alcohol will, in like manner, furnish a daily supply of nearly 350
lbs. of pure acid, and of other strengths in proportion. Theoretically,
the product should be 130 parts of the hydrated acid for every 100 parts
of alcohol consumed; but this is never quite obtained in practice, owing
to a small portion of the alcohol mixing with the newly formed acid, and
escaping decomposition; and from another small portion of both the
alcohol, and of the newly formed aldehyd, being carried off by the air
that permeates the apparatus. The platinum-powder does not waste, and the
most inferior spirit may generally be employed.
_Rationale._ In this process, the alcohol (as in other cases of
acetification) is first converted into aldehyd; and this, as rapidly as
formed, absorbs oxygen and passes into hydrated acetic acid. The
simultaneous formation of aldehyd during the oxygenation of that already
formed, may be detected by its odour.
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