Creative Chemistry: Descriptive of Recent Achievements in the Chemical IndustriesSlosson, Edwin E. (Edwin Emery)
Science
Creative Chemistry: Descriptive of Recent Achievements in the Chemical Industries
Slosson, Edwin E. (Edwin Emery)
Chemistry, Technical
consisted simply of a brick box fifteen feet long and seven feet wide
and deep, with big carbon electrodes at the ends. Between them was
packed a mixture of coke to supply the carbon, sand to supply the
silicon, sawdust to make the mass porous and salt to make it fusible.
[Illustration: The first American electric furnace, constructed by
Robert Hare of Philadelphia. From "Chemistry in America," by Edgar Fahs
Smith]
The substance thus produced at Niagara Falls is known as "carborundum"
south of the American-Canadian boundary and as "crystolon" north of this
line, as "carbolon" by another firm, and as "silicon carbide" by
chemists the world over. Since it is next to the diamond in hardness it
takes off metal faster than emery (aluminum oxide), using less power and
wasting less heat in futile fireworks. It is used for grindstones of
all sizes, including those the dentist uses on your teeth. It has
revolutionized shop-practice, for articles can be ground into shape
better and quicker than they can be cut. What is more, the artificial
abrasives do not injure the lungs of the operatives like sandstone. The
output of artificial abrasives in the United States and Canada for 1917
was:
Tons Value
Silicon carbide 8,323 $1,074,152
Aluminum oxide 48,463 6,969,387
A new use for carborundum was found during the war when Uncle Sam
assumed the role of Jove as "cloud-compeller." Acting on carborundum
with chlorine--also, you remember, a product of electrical
dissolution--the chlorine displaces the carbon, forming silicon
tetra-chloride (SiCl_{4}), a colorless liquid resembling chloroform.
When this comes in contact with moist air it gives off thick, white
fumes, for water decomposes it, giving a white powder (silicon
hydroxide) and hydrochloric acid. If ammonia is present the acid will
unite with it, giving further white fumes of the salt, ammonium
chloride. So a mixture of two parts of silicon chloride with one part of
dry ammonia was used in the war to produce smoke-screens for the
concealment of the movements of troops, batteries and vessels or put in
shells so the outlook could see where they burst and so get the range.
Titanium tetra-chloride, a similar substance, proved 50 per cent. better
than silicon, but phosphorus--which also we get from the electric
furnace--was the most effective mistifier of all.
Public-domain text, read in full here on John Shaqi.
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