Creative Chemistry: Descriptive of Recent Achievements in the Chemical IndustriesSlosson, Edwin E. (Edwin Emery)
Science
Creative Chemistry: Descriptive of Recent Achievements in the Chemical Industries
Slosson, Edwin E. (Edwin Emery)
Chemistry, Technical
This process is called "destructive distillation." What products come
off depends not only upon the composition of the particular variety of
coal used, but upon the heat, pressure and rapidity of distillation. The
way you run it depends upon what you are most anxious to have. If you
want illuminating gas you will leave in it the benzene. If you are after
the greatest yield of tar products, you impoverish the gas by taking out
the benzene and get a blue instead of a bright yellow flame. If all you
are after is cheap coke, you do not bother about the by-products, but
let them escape and burn as they please. The tourist passing across the
coal region at night could see through his car window the flames of
hundreds of old-fashioned bee-hive coke-ovens and if he were of
economical mind he might reflect that this display of fireworks was
costing the country $75,000,000 a year besides consuming the
irreplaceable fuel supply of the future. But since the gas was not
needed outside of the cities and since the coal tar, if it could be sold
at all, brought only a cent or two a gallon, how could the coke-makers
be expected to throw out their old bee-hive ovens and put in the
expensive retorts and towers necessary to the recovery of the
by-products? But within the last ten years the by-product ovens have
come into use and now nearly half our coke is made in them.
Although the products of destructive distillation vary within wide
limits, yet the following table may serve to give an approximate idea of
what may be got from a ton of soft coal:
1 ton of coal may give
Gas, 12,000 cubic feet
Liquor (Washings) ammonium sulfate (7-25 pounds)
Tar (120 pounds) benzene (10-20 pounds)
toluene (3 pounds)
xylene (1-1/2 pounds)
phenol (1/2 pound)
naphthalene (3/8 pound)
anthracene (1/4 pound)
pitch (80 pounds)
Coke (1200-1500 pounds)
When the tar is redistilled we get, among other things, the ten "crudes"
which are fundamental material for making dyes. Their names are:
benzene, toluene, xylene, phenol, cresol, naphthalene, anthracene,
methyl anthracene, phenanthrene and carbazol.
There! I had to introduce you to the whole receiving line, but now that
that ceremony is over we are at liberty to do as we do at a reception,
meet our old friends, get acquainted with one or two more and turn our
backs on the rest. Two of them, I am sure, you've met before, phenol,
which is common carbolic acid, and naphthalene, which we use for
mothballs. But notice one thing in passing, that not one of them is a
dye. They are all colorless liquids or white solids. Also they all have
an indescribable odor--all odors that you don't know are
indescribable--which gives them and their progeny, even when odorless,
the name of "aromatic compounds."
Public-domain text, read in full here on John Shaqi.
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